Gold pentafluoride

Apart from that of the recently synthesized gold pentafluoride (2), which was reported to be amorphous, the structures of all the transition metal pentafluorides are known. For all the compounds, cell dimensions have been derived, either from X-ray powder photographs or from single-crystal data. For seven of them structural analyses, at various levels of accuracy, have been performed on single-crystal data, and the remainder have unit-cell dimensions closely similar to a compound of known structure (see Table V). 

Pyrolysis of the krypton complex at between 60 and 65°C gave gold pentafluoride, AuF5 ... 

Gold (continued) pentafluoride, structure, 27 103 peroxides, 6 343-344 phthalocyanine, preparation of, 7 64 polyhalogen complex of, 3 153 poly(pyrazolyl)borato alkyl derivatives, 42 320-321... 

Carefully purified IF,-free iodine pentafluoride was melted onto O AuF contained in a quartz bulb. The gold salt dissolved in the IF5 to yield a bright red solution as oxygen smoothly evolved at 20 C. As the reaction proceeded to completion the red color faded... 

FjBrSCjHj, X -Sulfane, (2-bromo-ethenyl)pentafluoro>, 27 330 F5CH, Benzene, pentafluoro-, gold complexes, 26 86-90 FjCl, Chlorine pentafluoride, 29 7 FjCr, Chromium pentafluoride, 29 124 FjNOSC, X. -Sulfane, pentafluoro-(iso-cyanato)-, 29 38... 

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