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Glycopolymers strategies

Figure 15.3 Various strategies leading to dendronized or hyperbranched glycopolymers. (A) grafting of dendronsto pre-formed polymers (B) polymerization of dendron monomers (C) grafting dendrimers on pre-formed polymers... Figure 15.3 Various strategies leading to dendronized or hyperbranched glycopolymers. (A) grafting of dendronsto pre-formed polymers (B) polymerization of dendron monomers (C) grafting dendrimers on pre-formed polymers...
Scheme 5.14 Synthetic strategy for grafting hyperbranched glycopolymer from surfaces of MWCNTs by SCVCP of the inimer (AB ) and monomer (M) via ATRP. Reprinted with permission from Gao et al ... Scheme 5.14 Synthetic strategy for grafting hyperbranched glycopolymer from surfaces of MWCNTs by SCVCP of the inimer (AB ) and monomer (M) via ATRP. Reprinted with permission from Gao et al ...
The following section highlights five examples for the synthesis of glycopolymers via this post-polymerization strategy. [Pg.60]

The rest of this section covers the main strategies used for the synthesis of glycopolymers, particular highlighting recent selected examples. [Pg.83]

Recently, a Click polymerization strategy has been utilized to produce glycopolymers in which carbohydrates are incorporated into the backbone [198, 199]. Eissa and Khosravi demonstrated the copper wire-catalyzed Click polymerization of di-alkyne-terminated PEG with di-azide-functionalized trehalose prepared by tosylation/acetylation of a,a-D-trehalose followed by azidation reaction (Scheme 12) [199]. The produced alternating linear glycopolymers with triazole linkers were fully characterized and the polymer with a PEG segment of 600 gmol showed a lower critical solution temperature (LCST) at 39°C, which is known as the fever temperature. This material constituted a new class of temperature-responsive water-soluble glycopolymers. [Pg.96]

Roy R, Tropper FD, Romanowska A (1992) New strategy in glycopolymer syntheses -preparation of antigenic water-soluble poly(acrylamide-cp-para-acrylamidophenyl beta-lactoside). Bioconjug Chem 3(3) 256-261... [Pg.109]


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See also in sourсe #XX -- [ Pg.40 , Pg.41 , Pg.42 ]




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