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Glycol-cleavage reaction

The reaction is based, on the one hand, on the oxidative cleavage of vicinal diols by lead(IV) acetate and, on the other hand, on the reaction of dichlorofluorescein with lead(IV) acetate to yield a nonfluorescent oxidation product. The dichlorofluorescein only maintains its fluorescence in the chromatogram zones where the lead(IV) acetate has been consumed by the glycol cleavage reaction [1],... [Pg.326]

Sodium bismuthate (NaBiOa) was first used by Rigby as an oxidant for a-glycol cleavage reactions to give carbonyl compounds (equation 1), and was found to be similar in scope to lead tetraacetate and... [Pg.703]

While anodic oxidation of simple alcohols is of limited utility, direct oxidation of vicinal diols and related compounds is an excellent method for achieving oxidative cleavage to the corresponding carbonyl or carbonyl-acetal products, as in Eqs. (53) and (54). Unlike certain chemical glycol cleavage reactions, the anodic method is not limited by the stereochemistry of the substrate oxygens [132]. [Pg.613]

See other pages where Glycol-cleavage reaction is mentioned: [Pg.703]    [Pg.703]    [Pg.705]    [Pg.707]    [Pg.708]    [Pg.709]    [Pg.709]    [Pg.711]    [Pg.713]    [Pg.713]    [Pg.715]    [Pg.703]    [Pg.703]    [Pg.705]    [Pg.707]    [Pg.708]    [Pg.709]    [Pg.709]    [Pg.711]    [Pg.713]    [Pg.713]    [Pg.715]    [Pg.6]    [Pg.260]    [Pg.172]    [Pg.9]    [Pg.183]    [Pg.396]    [Pg.7]    [Pg.16]    [Pg.703]    [Pg.703]    [Pg.705]    [Pg.707]    [Pg.708]    [Pg.709]    [Pg.709]    [Pg.711]    [Pg.713]    [Pg.713]    [Pg.715]   
See also in sourсe #XX -- [ Pg.703 , Pg.704 , Pg.705 , Pg.706 , Pg.707 , Pg.708 , Pg.709 , Pg.710 , Pg.711 , Pg.712 , Pg.713 ]

See also in sourсe #XX -- [ Pg.703 , Pg.704 , Pg.705 , Pg.706 , Pg.707 , Pg.708 , Pg.709 , Pg.710 , Pg.711 , Pg.712 , Pg.713 ]

See also in sourсe #XX -- [ Pg.703 , Pg.704 , Pg.705 , Pg.706 , Pg.707 , Pg.708 , Pg.709 , Pg.710 , Pg.711 , Pg.712 , Pg.713 ]



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Cleavage reaction

Glycols reactions

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