Global Kinetic Model for NO Oxidation

Metkar et al. [9] developed a global kinetic model from a derivation of detailed reaction steps. They used reactions described in (12.11-12.14 [11]) and combined two reactions (see Eqs. 12.15-12.16 [11]). They received the best results when assuming the Eley-Rideal step, during the NO oxidation (Eq. 12.14) as rate determining. The resulting rate expression was  

The results from this global NO oxidation model is shown in Fig. 12.13 [9]. In this figure, results from both Fe-ZSM-5 (solid lines) and Cu-CHA are shown (dashed lines). The markers show the experimental points. The model accurately 

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