Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Generic equation of state

Iterative calculations using the implicit Eqs. (1.139) start with an initial value of Zvap close to one and an initial value of Ziiq cl°se 10 zero. Once the value of compressibility is obtained, then volume is obtained from V = ZRT/P. Table 1.3 lists the parameters for the generic equation of state. [Pg.25]

The generic equation of state presents two cases for the evaluation of tliis integral ... [Pg.205]

We derive the equation of state of an amphoteric surface by considering the generic dissociation reactions involving potential determining ions ... [Pg.100]

This equation does not fall within the compass of the generic cubic, Eq. (3.42) so we start anew. First, multiply the given equation of state by V/RT ... [Pg.654]

Example 1.10 Estimation of volume of a gas at high pressure using generic cubic equation of state... [Pg.25]

A generic cubic equation of state to calculate the molar volume is... [Pg.25]

Cubic Equations of State The simplest ejq)ressions that can (in principle) represent both the vapor- and liquid-phase volumetric behavior of pure fluids are equations cubic in molar volume. All such expressions are encompassed by the generic equation... [Pg.356]

Vapor Vapor-Like Roots of the Generic Cubic Equation of State... [Pg.92]

Any equation of state validfor gases in tlie zero-pessure limit implies a full set of virial coefficients. Show tliat the second and tliird virial coefficients implied ty tlie generic cubic equation of state, Eq. (3.41), are ... [Pg.111]

Cubic Equations of State The modern development of cubic equations of state started in 1949 with publication of the Redlich-Kwong (RK) equation [Chem. Rev., 44 233-244 (1949)], and many others have since been proposed. An extensive review is given by Valderrama [Ind. Eng. Chem. Res. 42 1603-1618 (2003)]. Of the equations published more recently, the two most popular are the Soave-Redlich-Kwong (SRK) equation, a modification of the RK equation [Chem. Eng. Sei. 27 1197-1203 (1972)] and the Peng-Robinson (PR) equation [Ind. Eng. Chem. Eundam. 15 59-64 (1976)]. All are encompased by a generic cubic equation of state, written as... [Pg.654]

Useful in the application of cubic equations of state to mixtures are partial equation-of-state parameters. For the parameters of the generic cubic, represented by Eqs. (4-104), (4-105), and (4-106), the definitions are... [Pg.676]

Similarly, in the equation of state (EOS) approach the problem consists of fitting parameters involved in the mixing rules, following the generic relation ... [Pg.202]

We see that many isotherm equations (linear, Volmer, Hill-deBoer, Harkins-Jura) can be derived from the generic Gibbs equation (2.3-13). Other equations of state relating the spreading pressure to the surface concentration can also be used, and thence isotherm equations can be obtained. The following table (Table 2.3-1) lists some of the fundamental isotherm equations from a number of equations of state (Ross and Olivier, 1964 Adamson, 1984). [Pg.34]


See other pages where Generic equation of state is mentioned: [Pg.26]    [Pg.114]    [Pg.52]    [Pg.53]    [Pg.55]    [Pg.26]    [Pg.26]    [Pg.114]    [Pg.52]    [Pg.53]    [Pg.55]    [Pg.26]    [Pg.307]    [Pg.243]    [Pg.88]    [Pg.92]    [Pg.662]    [Pg.665]    [Pg.260]    [Pg.91]    [Pg.673]    [Pg.676]    [Pg.138]    [Pg.92]    [Pg.19]    [Pg.22]    [Pg.158]    [Pg.668]   
See also in sourсe #XX -- [ Pg.25 ]

See also in sourсe #XX -- [ Pg.52 , Pg.55 ]

See also in sourсe #XX -- [ Pg.25 ]




SEARCH



Generic cubic equation of state

© 2024 chempedia.info