Galactomannan polysaccharide

Leguminosae). White powder odorless and tasteless but acquires a leguminous taste when boiled in water. A galactomannan polysaccharide. Mw 310,000 (approx). Insol in most org solvs. 

Less polysaccharide can also be used in products by taking advantage of the synergistic gelling of xanthan/galactomannan mixtures which forms thermoreversible gels at lower concentrations than if each is used separately. 

Three related galactomannans have been studied as films to 140 nm. These polysaccharides have a (1 4)-jS-D-mannopyranosyl backbone with (l- 6)-a-D-galactopyranosyl substituents (see formula 4). 

Delayed Crosslinking Additives. Glyoxal [458,460,461] is effective as a delay additive within a certain pH range. It bonds chemically with both boric acid and the borate ions to limit the number of borate ions initially available in solution for subsequent crosslinking of a hydratable polysaccharide (e.g., galactomannan). The subsequent rate of crosslinking of the polysaccharide can be controlled by adjusting the pH of the solution. 

The most characterised D-mannan degrading enzymes are the endo- -mannanases (5). These enzymes act on a range of 1,4-p-D-mannan-type polysaccharides including D-mannan, glucomannans (acetylated and deacetylated), galactomannans and galacto-glucomannans. The extent and... 

Assay and Purification of p-Mannanases. p-Mannanase can be specifically measured in crude enzyme mixtures with a dye-labelled carob galactomannan substrate (6), This substrate has a galactose content high enough (23%) to impart solubility to the substrate, but sufficiently low as not to interfere with the action of p-mannanases on the D-mannan backbone. The soluble dye-labelled substrate is incubated with enzyme preparation under controlled conditions and the reaction is terminated and unreacted dyed polysaccharide precipitated by ethanol addition. 

V. Interaction of Galactomannans with Carrageenan, Agar, and Other Polysaccharides. 284... 

Galactomannans have attracted considerable academic and industrial attention because of the central role they play in the area of polysaccharide interactions. On cooling even concentrated solutions... 

In describing and interpreting some of the more important properties of plant galactomannans, comparisons will be made with structurally similar polysaccharides, including the closely related glucomannans and galactoglucomannans, and those based on (1 — 4)-/3-D-xylan main-chains (for example, the arabinoxylans) and (1 — 4)-/3-D-glucan main-chains [for example, the amyloids and sodium 0-(carboxymethyl)cellulose]. 

---