Fris-Ligand synthesis

The family of heteroscorpionate ligands tailored around acetamidinate fragments disclosed by Smchez-Barba and coworkers constimtes another useful class of nitrogen-containing ancillaries particularly suited to the synthesis of heteroleptic Mg complexes, fri a first study [67], they prepared tbpamd MgR (R = C3H5, 31 ... 

In summary, simple amines are weakly coordinated ligands which are not appropriate for the synthesis of small spherical RuNPs in our reaction craiditions. Nevertheless, interesting worm-Uke shapes were observed, fri addition, the presence of amines allows the growth of preformed nuclei, which suggest the potential of amines for a shape-controlled synthesis of MNPs. This advantage was confirmed by results from other groups which reported sophisticated nanostructures displaying... 

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