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Freezing of the reaction

The application of helium permits the freezing of the reaction in such stages that the otherwise very reactive intermediates become detectable. Hydrogen thus influences the relative rates of elementary steps but not the overall meehanism which is shown in Fig. 4a (21,62). [Pg.284]

The coolant must not be poured directly into the bath, because local overcooling can cause partial freezing of the reaction mixture, which is clear and homogeneous before addition of the aldehyde. If freezing should occur, the flask is temporarily warmed slightly by removing the bath. [Pg.112]

It will be remembered that equilibrium does not imply total freezing of the reaction. It is characterized by a dynamic situation in which the reaction can proceed in both directions at a high rate. Equilibrium is reached when the forward and backward rates are equal and the net rate, which one would observe, say, as a change of concentration in a chemical reaction or a flow of current in the external circuit in an electrochemical reaction, is zero. [Pg.62]

Stage (3) Freezing of the reaction due to the slowing of molecular motion. [Pg.78]

To check this point, experiments were designed to control the freezing of the reaction solutimis [23]. Figure 10a shows the images of two equilibrium swollen PAMPS gel samples prepared at Tprep = —2 °C. Both the gel samples were prepared under identical conditions except for the initial temperature of the gelation system. In the case of the isothermal gel (1-gel), after addition of the initiator into... [Pg.127]

Quenching Rapid cooling from an elevated temperature, e.g., severe cooling of the reaction system in a short time (almost instantaneously), freezes the status of a reaction and prevents further decomposition or reaction. [Pg.165]

Temperature control at -15° to -25°C was also required for maximum yield. The best results were obtained by maintaining a temperature of -20 to -25°C during the addition of citral anil to the acid and at -15°C for the duration of the reaction. At this temperature range, the formation of a-cyclocitral (III) is favored. Higher temperatures caused excessive polymer formation and favored formation of e-cyclocitral whereas lower temperatures caused a reduction 1n the yield of the citral mixture. At least part of the problem with the lower temperature reaction was the fact that the sulfuric acid tended to freeze around the inside of the reaction vessel causing the effective molar ratio of acid to anil to be reduced. These lower temperature reaction mixtures were also lighter in color which indicated less polymer formation but this was accompanied by a lower yield of cyclocitrals. [Pg.419]

Dibenzyl Ether [Brpnsted Acid Promoted Reduction of an Aldehyde to a Symmetrical Ether].311 To a stirred solution of benzaldehyde (5.4 g, 0.05 mol) and TFA (11.4 g, 0.1 mol) under argon was added dropwise, with cooling, Et3SiH (8.1 g, 0.07 mol) at a rate such that the temperature of the reaction mixture did not exceed 40°. The solution turned a crimson color that gradually disappeared. Analysis by GLC showed the complete absence of the aldehyde immediately after addition of all of the silane. The products were separated by vacuum distillation at 20 Torr, collecting the fractions up to 125°. Dibenzyl ether was obtained from the residue by freezing out 4 g (0.02 mol, 80%) mp 3-6° nD25 1.5608. [Pg.122]

In from eight to ten hours up to 10 1. of acetylene are taken up. The colourless intermediate mercury compound very soon begins to separate. After the passing in of acetylene has ceased the whole of the reaction mixture is transferred to a round-bottomed flask and heated on a conical (Babo) air bath, while steam is passed through to decompose the mercury compound. The acetaldehyde liberated distils with the steam. An apparatus similar to that described under (a) is used one receiver containing ether and cooled in a freezing mixture is sufficient. The aldehyde is precipitated from the ethereal solution as aldehyde-ammonia in the manner described above. Yield of aldehyde-ammonia 5-6 g. [Pg.209]


See other pages where Freezing of the reaction is mentioned: [Pg.207]    [Pg.382]    [Pg.125]    [Pg.74]    [Pg.109]    [Pg.111]    [Pg.127]    [Pg.129]    [Pg.131]    [Pg.131]    [Pg.134]    [Pg.83]    [Pg.207]    [Pg.382]    [Pg.125]    [Pg.74]    [Pg.109]    [Pg.111]    [Pg.127]    [Pg.129]    [Pg.131]    [Pg.131]    [Pg.134]    [Pg.83]    [Pg.167]    [Pg.358]    [Pg.808]    [Pg.1005]    [Pg.427]    [Pg.526]    [Pg.1137]    [Pg.39]    [Pg.266]    [Pg.983]    [Pg.986]    [Pg.439]    [Pg.528]    [Pg.358]    [Pg.808]    [Pg.1232]    [Pg.567]    [Pg.159]    [Pg.231]    [Pg.63]    [Pg.134]    [Pg.126]    [Pg.250]    [Pg.462]    [Pg.286]    [Pg.2]   
See also in sourсe #XX -- [ Pg.78 ]




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