Free radicals substitution homolytic bimolecular reactions

A136. K. U. Ingold and B. P, Roberts, Free Radical Substitution Reactions Bimolecular Homolytic Substitutions (Sh2 Reactions) at Saturated Multivalent Atoms. Wiley (Interscience), New York, 1971. 245 pp. There is a section on Sa2 reactions in organo-group IV compounds,... 

Ingold, K.U. Roberts, B.P. Free Radical Substitution Reactions, Bimolecular Homolytic Substitution (Sg2 Reactions) at Saturated Multivalent Atom.s, Wiley-Interscience New York, 1971. 

A139. J. K. Kochi, ed., Free Radicals. Wiley (Interscience), New York, 1973. Vol. 1, 683 pp. Vol. 2, 852 pp. Volume 1, Chapter 6 contains a useful summary of organo-metallie-alkyl halide reactions, mainly involving RLi species. Chapter 10 by A. G. Davies and B. P. Roberts is entitled Bimolecular Homolytic Substitution at Metal Atoms." Volume 2 contains a chapter of 67 pp. (266) by H. Sakurai on group IVB radicals. 

The second publication is a review article by Ingold [390] on rate coefficients for free radical reactions in solution which includes comprehensive coverage of radical—molecule reactions. Metathetical reactions are usually referred to as Sn 2 reactions, i.e. substitution, homolytic and bimolecular, by organic chemists. Most quantitative kinetic studies of this class of solution reactions involve H atom transfer but halogen-transfer reactions have also been studied. 

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