Fluorochromate, potassium

Potassium superoxide. Pyridinium chlorochromate. Pyridinium dichromate. Pyridinium fluorochromate. Silver(I) oxide. Silver(II) oxide. Sodium chlorite. Sodium hypochlorite. Sodium periodate. Sodium peroxide. Thallium(in) trifluoroacetate. Trifluoroperacetic acid. [Pg.311]

Oxidation of several primary aliphatic alcohols with potassium dichromate, pyri-dinium dichromate, quinolinium dichromate (QDC), imidazolium dichromate, nico-tinium dichromate, isonicotinium dichromate, pyridinium fluorochromate (PFC), quinolinium fluorochromate, imidazolium fluorochromate, pyridinium chlorochromate (PCC), quinolinium chlorochromate (QCC), and pyridinium bromochromate (PBC), in aqueous acetic acid and in the presence of perchloric acid, showed similar kinetics. The values of the reaction constants did not differ significantly, indicating operation of a common mechanism.1... [Pg.85]

Salts of the trioxohalochromates(VI) [CrOsX]- (X = F, Cl, Table 113) can be crystallized from solutions of the appropriate dichromate and HX and have uses as oxidants of organic compounds. The fluorochromates can also be obtained from CrOs, HF and the alkali metal carbonate, and the chlorochromates from CrOs, MCI and HCl. Potassium trioxochlorochro-mate may also be prepared from K2Cr04 and CrOaCb- Salts of [CrOaBr]" and [CrOsI]" have been reported but they decompose through oxidation of the halide. [Pg.2783]