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Fluorinated free radicals

More recently, the possible contribution of organo-fluorine free radicals to ozone destruction has been considered with respect to the introduction of CFC transitional alternates and longer term replacements however, as discussed in Chapter 13.D, this also does not appear to be important in terms of ozone destruction. [Pg.673]

All aspects of the structure, reactivity and chemistry of fluorine-containing, carbon-based free radicals in solution are presented. The influence of fluorine substituents on the structure, the stability and the electronegativity of free radicals is discussed. The methods of generation of fluorinated radicals are summarized. A critical analysis of the reactivities of perfluoro-n-alkyl, branched chain perfluoroalkyl and partially-fluorinated free radicals towards alkene addition, H-atom abstraction, and towards intramolecular rearrangement reactions is presented. Lastly, a summary of the synthetically-useful chemistry of fluorinated radicals is presented. [Pg.97]

Dolbier WR jr. (1997) Fluorinated Free Radicals. 192 97-163 Dreizler RM (1996) Relativistic Density Functional Theory. 181 1-80 Driguez H (1997) Thiooligosaccharides in Glycobiology. 187 85-116 Dutasta J-P, see Collet A (1993) 165 103-129... [Pg.237]

See other pages where Fluorinated free radicals is mentioned: [Pg.245]    [Pg.262]    [Pg.97]    [Pg.99]    [Pg.101]    [Pg.103]    [Pg.105]    [Pg.107]    [Pg.107]    [Pg.109]    [Pg.111]    [Pg.113]    [Pg.115]    [Pg.117]    [Pg.119]    [Pg.121]    [Pg.123]    [Pg.125]    [Pg.127]    [Pg.129]    [Pg.131]    [Pg.133]    [Pg.135]    [Pg.137]    [Pg.139]    [Pg.141]    [Pg.143]    [Pg.145]    [Pg.147]    [Pg.149]    [Pg.151]    [Pg.153]    [Pg.155]    [Pg.157]    [Pg.159]    [Pg.161]    [Pg.164]    [Pg.254]    [Pg.255]    [Pg.223]    [Pg.197]    [Pg.237]    [Pg.211]    [Pg.204]    [Pg.105]   
See also in sourсe #XX -- [ Pg.999 , Pg.1000 ]



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FLUORINE-CONTAINING FREE RADICALS

Fluorinated aliphatic free radicals

Fluorination free radicals

Fluorination free radicals

Fluorination in (cont free-radical

Fluorination radical

Fluorine radicals

Mechanism free radical direct fluorination

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