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Fluonnation with hypofluonte

The heterocyclic system bimane produces a difluonnated product on fluonnation with acetyl hypofluonte [34 (equation 11)... [Pg.141]

Tnorganic and perfluoroorganic hypohalites add across olefimc bonds (equation 11 andTable 1) Thereactionsofhypofluontes have been included in a review on their chemistry [2J], In reactions of perfluoorganic hypofluontes, considerable fluonnation of the C=C bond may be observed With hypochlorites such as... [Pg.732]

Tnfluoromethyl hypofluonte will fluonnate Schiff bases, giving 7V,a,a-tn-fluoroamines and a-fluoroirmnes [144] and reacts with diazoketones to give adducts in modest yields [145] (equation 6) A-Substituted anridines give nng opened products by 1,3 addition of fluonne on nitrogen and tnfluoromethoxy on carbon [146] (equation 7)... [Pg.70]

Fluorine is well known for its ability to fluonnate selectively tertiary carbon-hydrogen bonds that are slightly activated by polar substituents Hypofluonte reagents also react with carbon-hydrogen bonds, both secondary and tertiary but tertiary bonds react better [6]... [Pg.146]

See other pages where Fluonnation with hypofluonte is mentioned: [Pg.70]    [Pg.70]    [Pg.70]    [Pg.72]   
See also in sourсe #XX -- [ Pg.143 ]

See also in sourсe #XX -- [ Pg.143 ]

See also in sourсe #XX -- [ Pg.143 ]



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Fluonnation

Fluonnation with

Fluonnation with acetyl hypofluonte

Hypofluontes

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