Fixed axis rotation model equation

In the fixed axis rotation model of dielectric relaxation of polar molecules a typical member of the assembly is a rigid dipole of moment p rotating about a fixed axis through its center. The dipole is specified by the angular coordinate < ) (the azimuth) so that it constitutes a system of 1 (rotational) degree of freedom. The fractional diffusion equation for the time evolution of the probability density function W(4>, t) in configuration space is given by Eq. (52) which we write here as... 

Furthermore, just as in the one-degree-of-freedom fixed-axis rotation model, in the high damping limit ((3 > 1), Eq. (282) can be simplified yielding the generalization to fractional dynamics of the Rocard [44] equation, namely,... 

In order to demonstrate how the anomalous relaxation behavior described by the hitherto empirical Eqs. (9)—(11) may be obtained from our fractional generalizations of the Fokker-Planck equation in configuration space (in effect, fractional Smoluchowski equations), Eq. (101), we first consider the fractional rotational motion of a fixed axis rotator [1], which for the normal diffusion is the first Debye model (see Section II.C). The orientation of the dipole is specified by the angular coordinate 4> (the azimuth) constituting a system of one rotational degree of freedom. Electrical interactions between the dipoles are ignored. 

This potential has two potential minima on the sites at <(> = 0 and = n as well as two energy barriers located at < ) = jt/2 and <[) = 3n/2. This model has been treated in detail for normal diffusion in Refs. 8,61, and 62. Here we consider the fractional Fokker-Planck equation [Eq. (55)] for a fixed axis rotator with dipole moment p moving in a potential [Eq. (163)]. 

We shall now demonstrate how the CTRW in the diffusion limit may be used to justify the fractional diffusion equation. We consider an assembly of permanent dipoles constrained to rotate about a fixed axis (the dipole is specified by the angular coordinate unit circle with fixed angular spacing A. We note that A may not necessarily be fixed for example, if we have a Gaussian distribution of jumps, the standard deviation of A serves as a fixed quantity. A typical dipole may remain in a fixed orientation at a given site for an arbitrary long waiting time. It may then reorient to another discrete orientation site. This is the discrete orientation model. 

Anomalous rotational diffusion in a potential may be treated by using the fractional equivalent of the diffusion equation in a potential [7], This diffusion equation allows one to include explicitly in Frohlich s model as generalized to fractional dynamics (i) the influence of the dissipative coupling to the heat bath on the Arrhenius (overbarrier) process and (ii) the influence of the fast (high-frequency) intrawell relaxation modes on the relaxation process. The fractional translational diffusion in a potential is discussed in detail in Refs. 7 and 31. Here, just as the fractional translational diffusion treated in Refs. 7 and 31, we consider fractional rotational subdiffusion (0rotation about fixed axis in a potential Vo(< >)- We suppose that a uniform field Fi (having been applied to the assembly of dipoles at a time t = oo so that equilibrium conditions prevail by the time t = 0) is switched off at t = 0. In addition, we suppose that the field is weak (i.e., pFj linear response condition). 

The first objective of this review is to describe a method of solution of the Langevin equations of motion of the itinerant oscillator model for rotation about a fixed axis in the massive cage limit, discarding the small oscillation approximation in the context of dielectric relaxation of polar molecules, this solution may be obtained using a matrix continued fraction method. The second... 

We first consider the A contribution. Equation 1, and an explanation in terms of a two-site model i.e., a model in which a water molecule exchanges between solution and sites (or class of sites) on or near a protein molecule such that at least one direction fixed in the water molecule is constrained to move rigidly with the protein molecule. In the simplest case, a water molecule attaches rigidly to the protein, moves with it for a while, and then leaves. In a somewhat more complex case, the attachment may be less rigid so that the water molecule is free to rotate about an axis fixed with respect to the protein. Additionally, a situation in which water molecules partially orient in the electric fields near the protein surface because of their electric dipole moments would also be a two-site model. Characteristic of a two site-model is that a time Tj, or a distribution of such times, can be defined that measures the mean lifetime of a water molecule in the protein-associated state. Moreover, such a time is in principle a measurable quantity, and its value must satisfy two criteria it must be at least comparable to if not longer than Tj, otherwise the nuclei of the bound water molecules could not sense the rotational motion of the protein molecules and it must be comparable to or shorter than the nuclear relaxation time of a bound water molecule, else it could not communi-... 

---