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Fischer projections drawing/using

Now, we need to draw the enantiomer. For Fischer projections, we use the method where we place a mirror on the side, and then we draw the reflection ... [Pg.162]

Using Fischer projections, draw the product of the reaction of D-mannose with... [Pg.727]

SampI Probl6m 27.2 Re-draw each Fischer projection formula using weages and dasnes for the stereogenic center, and... [Pg.1030]

Chemists commonly use two-dimensional representations called Fischer projections to show the configuration of carbohydrates. To draw a Fischer projection, draw a three-dimensional representation with the most oxidized carbon toward the top and the molecule oriented so that the vertical bonds from the stereocenter are directed away from you and the horizontal bonds from it are directed toward you. Then write the molecule as a two-dimensional figure with the stereocenter indicated by the point at which the bonds cross. You now have a Fischer projection. [Pg.588]

Fischer projections do not attempt to represent energy minimum conformations. Instead, they are designed to help distinguish the stereoisomers. An analogy would be the representation of substituted ethanes in an eclipsed conformation, called the sawhorse stmcture (p. 65). Fischer projections are used because they are simple to draw and read. We will see soon how to translate them into more accurate representations of molecules. [Pg.1127]

Fischer projection formulas can be used to represent molecules with several stereogenic centers and are commonly used for caibohydrates. For other types of structures, a more common practice is to draw the molecule in an extended conformation witii the main chain horizontal. In this arrangement, each tetrahedral caibon has two additional substituents, one facing out and one in. The orientation is specified widi solid wedged bonds for substituents facing out and with dashed bonds for substituents that point in. [Pg.85]

It is rather difficult to represent a tetrahedron which is three-dimensional with a drawing of a formula that is two-dimensional. Two types of representations are used, perspective and projection formulae. Fischer projections are widely used because of their simplicity. [Pg.273]

There is an entirely different way to draw stereocenters (instead of using regular bond-line drawings with dashes and wedges). Fischer projections are helpful for drawing molecules that have many stereocenters, one after another. These drawings look like this ... [Pg.158]

The molecule is twisting and bending around all of the time, and the conformation with the bracelet-shaped skeleton is just one of the possible conformations. The molecule probably spends very little of its time like this (it is a relatively high energy conformation), but this is the conformation that we will use to draw our Fischer projection. [Pg.159]

Now we can understand why we cannot draw a Fischer projection sideways. If we did, we would be inverting the stereocenter. To draw the enantiomer of a Fischer projection, do not turn the drawing sideways. Instead, you should use the second method we saw for drawing enantiomers (place the mirror on the side of the compound and draw the reflection). Recall that this was the method that we used for drawings where wedges and dashes were implied but not shown. Fischer projections are another example of drawings that fit this criterion ... [Pg.161]

Problem 5.17 Draw three-dimensional and Fischer projections, using superscripts to show priorities, for (a) (S)-2-bromopropanaldehyde, (6) (R)-3-iodo-2-chloropropanol. ... [Pg.76]

Redraw the perspective drawings a, b, and c as Fischer projection formulas, leaving the configuration at the chiral centers unchanged. Similarly, redraw d and e in perspective, using a staggered sawhorse representation for e. [Pg.148]

Which of the following compounds are chiral Draw each compound in its most symmetric conformation, star ( ) any asymmetric carbon atoms, and draw any mirror planes. Label any meso compounds. You may use Fischer projections if you prefer. [Pg.206]

Use perspective drawings and Fischer projections to show the stereochemistry of D- and L-amino acids. Explain why the naturally occurring amino acids are called L-amino acids. Problems 24-37 and 53... [Pg.1195]

Problom 27.2 Draw each stereogenic center using a Fischer projection formula. [Pg.1030]

Although more representative of the actual structure of a compound, stereochemical structures are often difficult to draw quickly. An alternative method of depicting structures with tetrahedral carbon centers relies on the use of Fischer projections. [Pg.52]


See other pages where Fischer projections drawing/using is mentioned: [Pg.177]    [Pg.198]    [Pg.187]    [Pg.192]    [Pg.159]    [Pg.157]    [Pg.14]    [Pg.161]    [Pg.102]    [Pg.318]    [Pg.277]    [Pg.277]    [Pg.6]    [Pg.240]    [Pg.200]    [Pg.217]    [Pg.1102]    [Pg.1153]    [Pg.167]    [Pg.1073]    [Pg.47]    [Pg.53]    [Pg.1075]    [Pg.1095]   
See also in sourсe #XX -- [ Pg.223 , Pg.224 ]

See also in sourсe #XX -- [ Pg.216 ]




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