Fire plumes with combustion

The model is a straightforward extension of a pool-fire model developed by Steward (1964), and is, of course, a drastic simplification of reality. Figure 5.4 illustrates the model, consisting of a two-dimensional, turbulent-flame front propagating at a given, constant velocity S into a stagnant mixture of depth d. The flame base of width W is dependent on the combustion process in the buoyant plume above the flame base. This fire plume is fed by an unbumt mixture that flows in with velocity Mq. The model assumes that the combustion process is fully convection-controlled, and therefore, fully determined by entrainment of air into the buoyant fire plume. 

Combustion is an exothermic reaction in which reactants are converted to principally gaseous products. Because the reaction is exothermic, the product gases heat up and expand. In a fire, such as arson, this expansion generates plumes with predictable behaviors that leave distinctive markings at the crime scene. In contrast, propellants rely on expansion of hot gases to drive a projectile forward, while explosives confine the expansion as long as possible to generate a destructive shock wave. Because of this confinement, a detonation is a... 

Combustion behavior differed in some respects between continuous and instantaneous spills, and also between LNG and refrigerated liquid propane. For continuous spills, a short period of premixed burning occurred immediately after ignition. This was characterized by a weakly luminous flame, and was followed by combustion of the fuel-rich portions of the plume, which burned with a rather low, bright yellow flame. Hame height increased markedly as soon as the fire burned back to the liquid pool at the spill point, and assumed the tilted, cylindrical shape that is characteristic of a pool fire. 

The characteristics of several QCM instruments for aerosol measurement have been reviewed (ll). Particles are collected by impaction, electrostatic precipitation or both. The mass sensitivity is reported to be affected by the location of deposited particles on the crystal, the size of the particles, and the type of coating. In addition, the sensitivity changes as the crystal becomes loaded. Despite some limitations, most of the studies Indicated that QCMs can be successfully used for aerosol measurement with good correlation coefficient with the reference filtration method. Applications included measurement of aerosol in ambient air, particulate emission from automobiles and diesel engines, smoke plume from a coal-fired power plant, solid fueled rocket plvune, and particulate matter in the effluents in combustion sources. 

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