Figure Inserts

Figure 2. Inhibition of eel AChE by ANTX-A(S) - the secondary plot. P, the first-order rate constant which was the rate of inhibition at that ANTX-A(S) concentration obtained from the primary plot (insert). The intercept on the 1/P axis is 1/k and the intercept on the 1/[I] axis is -1/K. Figure insert Progressive irreversible inhibition of eel AChE by ANTX-A(S). The inactivation followed first-order kinetics. ANTX-A(S) concentrations, xg/mL (A) 0.083 ( ) 0.166 (o) 0.331 ( ) 0.497 (V) 0.599 ( ) control. Each point represents the mean of 3 or 4 determinations.

Indexes Author Index Subject Index Color Figure Inserts... 

Figure 3.8. The time dependence of the intensities of Raman scattering for vibrational modes of trans-stilben. The figure insert displays a fitting. [Reprinted with permission from S. L. Schultz, J. Qian, and J. M. Jean, J. Phys. Chem., AlOl (1997), p. 1000. Copyright 1997, American Chemical Society.]...

It is therefore very interesting to estimate a leak rate suitable for use in safety analyses, leaving unchanged the figure inserted in the technical specifications for the maximum leak rate to be demonstrated through periodical tests. 

Figure 13. Typical plots of 17 and r 2 against c.d. on Pd wire electrode (0.2-mm diameter) in 0.5 M H2SO4 (Enyo and Maoka ). The arrow indicates i ot evaluated from the polarization resistance at low r 2 (the figure inserted).

Figure 3 Test object no. 1, graphite central cylinder inserted in a lucite and aluminum...

Figure A3.13.12. Evolution of the probability for a right-handed ehiral stmetnre (fiill eiirve, see ( equation (A3,13.69))) of the CH eliromophore in CHD2T (a) and CHDT2 ( ) after preparation of ehiral stnietures with multiphoton laser exeitation, as diseussed in the text (see also [154]). For eomparison, the time evolution of aeeording to a one-dimensional model ineluding only the bending mode (dashed enrve) is also shown. The left-hand side insert shows the time evolution of within the one-dimensional ealeulations for a longer time interval the right-hand insert shows the time evolution within the tln-ee-dimensional ealeulation for the same time interval (see text).

The phase of a transition in a CIDNP speetnim ean be detennined rising niles developed by Kaptein [20]. The nile for the net effeet is shown in equation (Bl.16.6). For eaeh tenn, the sign (-t or -) of that value is inserted, and the final sign detennines the phase of the polarization phis is absorptive and minns is emissive. The variables are defined in the eaption to figure B 1.16.7. 

Figure Bl.17.12. Time-resolved visualization of the dissociation of myosin SI from filamentous actin (see also figure Bl.17.6). Shown are selected filament images before and after the release of a nucleotide analogue (AMPPNP) by photolysis (a) before flashing, (b) 20 ms, (c) 30 ms, (d) 80 ms and (e) 2 s after flashing. Note the change in obvious order (as shown by the diffraction insert in (a)) and the total dissociation of the complex in (e). The scale bar represents 35.4 mn. Picture with the courtesy of Academic Press.

Figure B3.3.8. Insertion probability for hard spheres of various diameters (indieated on the right) in the hard sphere fluid, as a fiinetion of paeking fraetion p, predieted using sealed partiele theory. The dashed line is a guide to the lowest aeeeptable value for ehemieal potential estimation by the simple Widom method.

Another triek is applieable to, say, a two-eomponent mixture, in whieh one of the speeies. A, is smaller than the other, B. From figure B3.3.8 for hard spheres, we ean see that A need not be particularly small in order for the test partiele insertion probability to elimb to aeeeptable levels, even when insertion of B would almost always fail. In these eireumstanees, the ehemieal potential of A may be detemiined direetly, while that of B is evaluated indireetly, relative to that of A. The related semi-grand ensemble has been diseussed in some detail by Kofke and Glandt [110]. 

In this section, we insert explicitly. The sum has the following meaning for each pair of points x and a draw a path j (t) that starts at x (j (t = 0) = a ) and ends at x" (j (t = r) = a ). This path need not be a classical patii (see figure B3.4.15). Each such path contributes c where S is the action of the path. S (iimelated to the scattering matrix) is calculated very simply as... 

Figure 2.6. The tetrahedral structures of ice (a), (fc) are planes through sheets of selected oxygen nuclei (open circles), hydrogen nuclei (shotm in the insert as solid circles) are not shown in the main drawing. The insert illustrates the overlap of oxygen line pairs and the hydrogen nuclei, thus forming the hydrogen bonds (dotted lines)...

The full ab-initio molecular dynamics simulation revealed the insertion of ethylene into the Zr-C bond, leading to propyl formation. The dynamics simulations showed that this first step in ethylene polymerisation is extremely fast. Figure 2 shows the distance between the carbon atoms in ethylene and between an ethylene carbon and the methyl carbon, from which it follows that the insertion time is only about 170 fs. This observation suggests the absence of any significant barrier of activation at this stage of the polymerisation process, and for this catalyst. The absence or very small value of a barrier for insertion of ethylene into a bis-cyclopentadienyl titanocene or zirconocene has also been confirmed by static quantum simulations reported independently... 

The ROSDAL syntax is characterized by a simple coding of a chemical structure using alphanumeric symbols which can easily be learned by a chemist [14]. In the linear structure representation, each atom of the structure is arbitrarily assigned a unique number, except for the hydrogen atoms. Carbon atoms are shown in the notation only by digits. The other types of atoms carry, in addition, their atomic symbol. In order to describe the bonds between atoms, bond symbols are inserted between the atom numbers. Branches are marked and separated from the other parts of the code by commas [15, 16] (Figure 2-9). The ROSDAL linear notation is rmambiguous but not unique. 

Both tables, the atom and the bond lists, are linked through the atom indices. An alternative coimection table in the form of a redundant CT is shown in Figure 2-21. There, the first two columns give the index of an atom and the corresponding element symbol. The bond list is integrated into a tabular form in which the atoms are defined. Thus, the bond list extends the table behind the first two columns of the atom list. An atom can be bonded to several other atoms the atom with index 1 is connected to the atoms 2, 4, 5, and 6. These can also be written on one line. Then, a given row contains a focused atom in the atom list, followed by the indices of all the atoms to which this atom is bonded. Additionally, the bond orders are inserted directly following the atom in-... 

The insertion of a three-unit molecule onto the lattice shown, starting at point S, can he achieved in only ay (see text). (Figure adapted from Siepmann J11990. A Method for the Direct Calculation of Chemical tialsfor Dense Chain Systems. Molecular Physics 70 1145-1158.)... 

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