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Fick’s diffusion coefficient

Here Dk is Fick s diffusion coefficient, kB Boltzmann s constant, T the temperature, p the total mass density, vk the partial specific volume, g the acceleration of gravity. By working out the imperfection theory for... [Pg.182]

Cross-flow FFF (F1FFF) utilizes a second fluid flow to transport sample components across the channel thickness to the accumulation wall, and the position of individual species in the laminar carrier profile corresponds to their ordinary (Fick s) diffusion coefficient. As the particle size increases, the diffusion coefficient (decreases until it becomes a relatively insignificant transport process. For micron-size particles, the extent of protrusion into the channel becomes the decisive factor in determining the order of elution. [Pg.502]

For translational long-range jump diffusion of a lattice gas the stochastic theory (random walk, Markov process and master equation) [30] eventually yields the result that Gg(r,t) can be identified with the solution (for a point-like source) of the macroscopic diffusion equation, which is identical to Pick s second law of diffusion but with the tracer (self diffusion) coefficient D instead of the chemical or Fick s diffusion coefficient. [Pg.793]


See also in sourсe #XX -- [ Pg.204 ]




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