Ferric acetyl acetonate

Amorphous (most likely atactic) 3,4-polyisoprene of 94—100% 3,4-microstmcture was prepared with a (C2H 3A1—Ti(0—/ -C Hy) catalyst (11). Crystalline 3,4-polyisoprene containing about 70% 3,4-units and about 30% i7j -l,4-microstmcture was prepared using a catalyst derived from iron acetyl acetonate, trialkyl aluminum, and an amine in benzene (37). However, this polyisoprene contained gel and was obtained in poor yield. Essentially gel-free crystallizable 3,4-polyisoprene of 70—85% 3,4-microstmcture with the remainder being cis-1,4 microstmcture was prepared in conversions of greater than 95% with a water-modified tri alkyl aluminum, ferric acetyl acetonate, and 1,10-phenanthroline catalyst (38). The 3,4-polyisoprene is stereoregular and beheved to be syndiotactic or isotactic. 

Examples of the components of the gelling composition are a water-soluble polymer such as polyacrylamide, an iron compound such as ferric acetyl-acetonate or ammonium ferric oxalate, and a ketone such as 2,4-pentanedione [1247]. The composition forms a temporary gel that is useful for the temporary plugging of a formation. The temporary gels that are formed will disappear after 6 months. 

L.H. Caveny et al, Evaluation of Additives to Reduce Solid Propellant Flammability in Ambient Air , BRL Contract Rept 278, Princeton Univ, Princeton, Contract DAAD05-72-C-0135) (1975) (ADA-019108), 15,17, 73 [The authors expts show that addn of 10% tritotyl phosphate is the most effective means of lowering the mass burning rate and reducing flammability limits of a control HMX composite pro-pint. The proplnt compn consisted of HMX/-3,3 -bitolylene 4,4 -diisocyanate, hydroxyl-terminated polyethylene oxide of 400 mw, trime-thylolpropane trimethacrylate and ferric acetyl-acetonate (75/25%)] 62) N. Kubota T. 

Polypropylene glycol 2025 (PPG) Ferric acetyl acetonate (FAA) Tolylene diisocyanate (TDI) 1,2,6-Hexanetriol (HT)... 

Anotner organic ferric compotuid,namely the ferric acetyl acetonate (PemAcAo) has been found to be an effective initiator for the photodegradation of polyethylene (65) and poly(vinyl chloride)(66). These ferric compounds are easily oxidized and photolyz eT. The following mechanism for radical formation in polyethylene sample was proposed (67,68)1... 

There are many other iron complexes of a similar nature yet to be investigated including many model complexes such as cupferron and ferric acetyl acetonate as well as the hydroxamates and the catechols. 

Fig. 5. Variation of normalized activation energy with concentration of DBTDL and ferric acetyl acetonate for the catalyzed polymerization of BACY...

Fig. 4.7 Influence of 4.5% dispersant and 1% calcium sulphonate detergent on the antioxidant performance of a 0.1%P ZnDTP. 150SN, S = 0.3% base stock, temperature 165°C air flow 1.7 1 min 40 ppm Fe catalyst as ferric acetyl acetonate...

Other organic active hydrogen compounds such as acetylacetone (AAH), hexafluoroacetylacetone, dibenzoylmethane, and 8-hydroxy-quinoline gave similar photochemical oxidative decarbonylation reactions 188,383), a preparative application is the preparation of ferric acetyl-acetonate according to Eq. (35) ... 

Evaluating a single catalyst, the fastest cure rate is when ferric acetylacetonate is used in the system. In high concentrations, cobalt napthanate alone and combined with cobalt octoate, offer a fast reaction rate. Yet, when ferric acetyl acetonate is combined with cobalt napthanate or cobalt octoate, the reaction rate increases. For this system, the increased amount of catalyst yields a decrease in cure time. There is no direct correlation between length of time specimens were was subjected to heat and cure rate. 

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