Eyring absolute rate theory

H. M. Rosenstock, M. B. Wallenstein, A. L. Wahrhaftig, and H. Eyring, Absolute rate theory for isolated systems and the mass spectra of polyatomic molecules, Proc. Natl. Acad. Sci. USA 38 667 (1952). 

The most widely accepted treatment of reaction rates is transition state theory (TST), devised by Henry Eyring.17 It has also been known as absolute rate theory and activated complex theory, but these terms are now less widely used. 

Rosenstock, H.M. Wallenstein, M.B. Wahihaftig, A.L. Eyring, H. Absolute Rate Theory for Isolated Systems and the Mass Spectra of Polyatomic Molecules. 

Detonation, Absolute Reaction Rate Theory of Eyring or Activated Complex Theory. See Absolute Rate Theory in Vol 1 of Encycl, p A4-R and in Cook (1958), p 134... 

Eyring (1935a, b) developed Transition State Theory , or Absolute Rate Theory , in the 1930s. 

According to Eyring s absolute rate theory (1), in which there is postulated the establishment of a quasiequilibrium between the reactants and an active complex, the rate constant may be expressed as... 

Eyring absolute reaction rate theory see Absolute rate theory 1 A4 6 E508... 

Work on the development of the modern theory of the charge-transfer overpotential started when Eyring and Wynne-Jones and Eyring formulated the absolute rate theory on the basis of statistical mechanics [3,4], This expresses the rate constant k of a chemical reaction in terms of the activation energy AG, Boltzmann s constant k% and Planck s constant h... 

The theory of activated rate processes originates with Arrhenius (2), who, inspired by van t Hoff, demonstrated that the temperature dependence of the rate of change of optical isomers is characterized by an activation energy Et. Forty years of intensive research on activated reactions culminated with Eyring s famous paper on the absolute rate theory (3) and the deceptively simple expression... 

R. A. Marcus and O. K. Rice, /. Phys. Colloid Chem., 55, 894 (1951). The Kinetics of the Recombination of Methyl Radicals and Iodine Atoms. R. A. Marcus, /. Chem. Phys., 20, 352 (1952). Lifetimes of Active Molecules. I. H. M. Rosenstock, M. B. Wallenstein, A. L. Wah aftig, and H. Eyring, Proc. Natl. Acad. Sci. USA, 38, 667 (1952). Absolute Rate Theory for Isolated Systems and the Mass Spectra of Polyatomic Molecules. 

The viscosity of a liquid mixture, y, can be calculated from the Eyring s absolute rate theory ... 

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