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Expression of the Electron Transfer Rate for a Non-adiabatic Process

1 Expression of the Electron Transfer Rate for a Non-adiabatic Process [Pg.6]

Electron transfer processes induce variations in the occupancy and/or the nature of orbitals which are essentially localized at the redox centers. However, these centers are embedded in a complex dielectric medium whose geometry and polarization depend on the redox state of the system. In addition, a finite delocalization of the centers orbitals through the medium is essential to-promote long-range electron transfers. The electron transfer process must therefore be viewed as a transition between two states of the whole system. The expression of the probability per unit time of this transition may be calculated by the general formahsm of Quantum Mechanics. [Pg.6]




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Adiabatic electron transfer

Adiabatic process

Adiabatic transfer

Adiabaticity of electron transfer

Adiabaticity, electronic

Electron processes

Electron transfer adiabaticity

Electron-transfer processes

Electronic processes

Electronically adiabatic

Electronically adiabatic processes

Electronically non-adiabatic processe

Expression for

Non-adiabatic electron transfer

Non-adiabatic processes

Non-adiabatic transfer

Non-adiabaticity

Processing rate

Rate expression, for electron transfer

Rate expressions

Rate for As

Rate of As

Rate of transfer

Rate processes

Rates of electron transfer

The Electron Transfer Process

The a-process

Transfer of electron

Transfer rate

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