Experimental and calculated molar

Furthermore, the values of the experimental and calculated molar rotatory power are in good agreement in the case of polymers having the... 

Table III. Comparison of Experimental and Calculated Molar Volumes for Carbon Dioxide + Methyl Oleate at 313.15 K ...

Both the experimental and calculated molar volumes show that the molar volume of the vapor phase becomes smaller than that of the liquid at higher pressures. This seemingly anomalous result is a consequence of the very large difference in molecular weights of the solute and solvent. We saw no evidence, such as a phase inversion, that the mass densities of the liquid and vapor become equal except at the critical point on the isotherm. 

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