Large excursions

The accident at the Three Mile Island (TMI) plant in Pennsylvania in 1979 led to many safety and environmental improvements (4—6). No harm from radiation resulted to TMI workers, to the pubHc, or to the environment (7,8), although the accident caused the loss of a 2 x 10 investment. The accident at the Chernobyl plant in the Ukraine in 1986, on the other hand, caused the deaths of 31 workers from high doses of radiation, increased the chance of cancer later in life for thousands of people, and led to radioactive contamination of large areas. This latter accident was unique to Soviet-sponsored nuclear power. The Soviet-designed Chemobyl-type reactors did not have the intrinsic protection against a mnaway power excursion that is requited in the test of the world, not was there a containment building (9—11). 

Criticality Precautions. The presence of a critical mass of Pu ia a container can result ia a fission chain reaction. Lethal amounts of gamma and neutron radiation are emitted, and a large amount of heat is produced. The assembly can simmer near critical or can make repeated critical excursions. The generation of heat results eventually ia an explosion which destroys the assembly. The quantity of Pu required for a critical mass depends on several factors the form and concentration of the Pu, the geometry of the system, the presence of moderators (water, hydrogen-rich compounds such as polyethylene, cadmium, etc), the proximity of neutron reflectors, the presence of nuclear poisons, and the potential iateraction with neighboring fissile systems (188). As Httle as 509 g of Pu(N02)4 solution at a concentration Pu of 33 g/L ia a spherical container, reflected by an infinite amount of water, is a critical mass (189,190). Evaluation of criticaUty controls is available (32,190). 

Heat Release and Reactor Stability. Highly exothermic reactions, such as with phthaHc anhydride manufacture or Fischer-Tropsch synthesis, compounded with the low thermal conductivity of catalyst peUets, make fixed-bed reactors vulnerable to temperature excursions and mnaways. The larger fixed-bed reactors are more difficult to control and thus may limit the reactions to jacketed bundles of tubes with diameters under - 5 cm. The concerns may even be sufficiently large to favor the more complex but back-mixed slurry reactors. 

Pitting had two distinct causes. Sulfate reducers had formed the large hemispherical pits. The more undercut pits were formed during a low-pH excursion involving mineral acid after the sulfate-reducing bacteria became inactive. It is likely the low-pH excursion deepened preexisting sulfate-reducer pits, causing final perforation. 

Monitor water routinely for pH excursions in all large cooling systems. 

The reaction is exothermic and so to avoid serious temperature excursions the reactor consists of a bundle of narrow tubes, each a few centimeters in diameter, surrounded by a heat transfer medium. The catalyst consists of relatively large silver particles on an inert a-Al203 support. The surface area is below 1 m g". Promoters such as potassium and chlorine help to boost the selectivity from typically 60% for the unpromoted catalysts to around 90%, at ethylene conversion levels of the order of50%. 

Figure 2.14 Relation between the EEG recorded from an epileptic focus on the surface of the cerebral cortex (EEG) and the activity of a single cortical neuron recorded extracellularly (e.c.) and intracellularly (i.c.) during an experimental epilepsy induced by topical application of penicillin. Note that the large EEG excursions correspond to the large (synchronised) depolarisations of the neuron, not to action potential discharges. (Adapted from Brain Res. 52 Ayala, GF et al. Genesis of Epileptic Interictal Spikes. New Knowledge of Cortical Feedback systems suggests a Neurophysiological Explanation of Brief Paroxysms, 1-17 (1973) with permission from Elsevier Science)...

Flow undergoes a sudden, large-amplitude excursion, to a new, stable operating condition... 

---