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Exchange-Cleavage

Vinyllead and alkynyllead tricarboxylates can only be prepared by metal-metal exchange, such as mercury-lead,ll6 ll7 tin-lead,ll6,ll7 boron-lead i or zinc-lead.l In the case of tin-lead exchange, cleavage of the methyl-tin bond is much slower than cleavage of the vinyl-tin or alkynyl-tin bond. Therefore (trimethyl)vinyltin derivatives are preferred to the corresponding (tributyl)vinyltin analogues for the synthesis of the unstable vinyllead and alkynyllead compounds. [Pg.215]

After cleavage the reaction mass is a mixture of phenol, acetone, and a variety of other products such as cumylphenols, acetophenone, dimethyl-phenylcarbinol, a-methylstyrene, and hydroxyacetone. It may be neutralised with a sodium phenoxide solution (20) or other suitable base or ion-exchange resins. Process water may be added to facilitate removal of any inorganic salts. The product may then go through a separation and a wash stage, or go direcdy to a distillation tower. [Pg.96]

MgBr reagent by an exchange reaction, while the 4-chloro derivative undergoes reductive cleavage (Scheme 90) (63AHC(2)365). [Pg.58]

Thiazole, 2-acetylamino-4-methyl-alkylation, 6, 256 Thiazole, 2-acylamino-4-hydroxy-synthesis, 6, 297 Thiazole, 5-alkoxy-cleavage, 6, 289 synthesis, 6, 302 Thiazole, 2-alkyl-A7-alkylation, 6, 253 hydrogen exchange, 6, 276 methylation, 6, 253 quatemization, 6, 253-254 reactions, S, 88 Thiazole, 4-alkyl-A7-alkylation, 6, 253 methylation, 6, 253 quatemization, 6, 253-254 Thiazole, 5-alkyl-A7-alkylation, 6, 253 methylation, 6, 253 Thiazole, 2-alkylamino-tautomerism, 6, 248 Thiazole, 4-alkyl-2,5-dimethyl-quatemization, 6, 253-254 Thiazole, 2-alkylthio-reactions, S, 103 rearrangement, 5, 103 6, 291 Thiazole, 3-allyl-4-hydroxy-2-imino-synthesis, 6, 297 Thiazole, 2-allyloxy-rearrangement, 6, 289 Thiazole, 2-amino-diazo coupling, 6, 257 nitration, 6, 255... [Pg.871]

The DNP derivative, prepared from 2,4-dinitrofluorobenzene is released from the nitrogen with an anionic ion exchange resin." When used for histidine protection, the DNP group has been observed to migrate to nearby [ysine residues during Fmoc cleavage. ... [Pg.578]

Protection of primary aryl amines as the triazene is accomplished by diazotiza-tion of the amine followed by reaction with pyrrolidine in aq. KOH. This group is stable to metalation of the aromatic ring by metal halogen exchange. The amine is recovered by reductive cleavage with Ni-Al alloy (aq. KOH, rt, 37-68% yield). ... [Pg.597]

Eda and Kurth applied a similar solid-phase combinatorial strategy for synthesis of pyridinium, tetrahydropyridine, and piperidine frameworks as potential inhibitors of vesicular acetylcholine transporter. One member of the small library produced was prepared from amino-functionalized trityl resin reacting with a 4-phenyl Zincke salt to give resin-bound product 62 (Scheme 8.4.21). After ion exchange and cleavage from the resin, pyridinium 63 was isolated. Alternatively, borohydride reduction of 62 led to the 1,2,3,6-tetrahydropyridine 64, which could be hydrogenated to the corresponding piperidine 65. [Pg.364]


See other pages where Exchange-Cleavage is mentioned: [Pg.84]    [Pg.85]    [Pg.93]    [Pg.94]    [Pg.95]    [Pg.375]    [Pg.84]    [Pg.85]    [Pg.93]    [Pg.94]    [Pg.95]    [Pg.375]    [Pg.168]    [Pg.282]    [Pg.114]    [Pg.289]    [Pg.200]    [Pg.91]    [Pg.315]    [Pg.87]    [Pg.69]    [Pg.691]    [Pg.729]    [Pg.883]    [Pg.387]    [Pg.189]    [Pg.1069]    [Pg.364]    [Pg.21]    [Pg.414]    [Pg.18]    [Pg.60]    [Pg.61]    [Pg.131]    [Pg.94]    [Pg.156]    [Pg.222]    [Pg.169]    [Pg.434]    [Pg.436]    [Pg.515]    [Pg.516]    [Pg.519]    [Pg.536]   


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Proton Cleavage, heterolytic Exchange processes

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