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Example 3 a Hybrid Salt-Co-crystal

Building unit formed by one molecule of (grey), two molecules of A (black) and two molecules of AH (orange) adapted from Ref 6. [Pg.306]

3 Co-crystals of Alike Molecules (including Enantiomers, Isomers, Diastereomers. ..) [Pg.306]

When two components are mirror related molecules (i.e. optical antipodes or enantiomers), special relationships link them. For instance, they have equal non-vectorial intensive properties (temperature and enthalpy of fusion, etc.) and are opposite in sign but have equal absolute values of vectorial properties [Pg.306]

Although there is a priori no restriction in symmetry applicable to the space group of the racemic compound crystal lattice, a clear majority of these racemic compounds crystallize in one of the 92 centrosymmetric space groups among them Fife, P-l, C2/c, Pbca, Pnma are by far the most popular. . [Pg.307]

Some chiral racemic compounds crystallize in the 73 non-chiral and non-centrosymmetric space groups such as Pc, Pnali (form III of rae modafi-niii8,i9) Fddl (form IV rac-modafiniP°), and so on. Very rare examples [Pg.307]


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