Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Euler construction

The theory for this problem is well known. The following necessary condition, which must be satisfied, is Euler s equation for isoperimetric problems (usually used to construct the solution) ... [Pg.306]

The Beilinson spectral sequence. Let A be the diagonal in P x P. First, we shall construct a resolution of Oa which has certain nice properties. Let p P x P be the projection to the Ath factor. We denote by Q the locally free sheaf on P of rank 2 which is dehned by the following Euler sequence,... [Pg.14]

As indicated in Fig. 7, the next step after either an explicit or an implicit energy density functional orbit optimization procedure. For this purpose, one introduces the auxiliary functional Q[p(r) made up of the energy functional [p(r) 9 ]. plus the auxiliary conditions which must be imposed on the variational magnitudes. Notice that there are many ways of carrying out this variation, but that - in general - one obtains Euler-Lagrange equations by setting W[p(r) = 0. [Pg.206]

A major complication exists for constructing the Lagrangian density of a pair of particles diffusing relative to each other. The diffusion (Euler) equation is dissipative and the density of the diffusing species is not conserved. The Euler density, p, would lead to a space—time invariant, Sfr, which would not be constant. This difficulty requires the same approach as that used to handle the Schrodinger equation. Morse and Feshbach [499] define a reverse or backward diffusion equation where time goes backwards compared with that in eqn. (254)... [Pg.301]

This approach to defining the Lagrangian density with the aid of both forward and backward Euler densities ip and ip uses the neat construct that ip ip is time-invariant. This is as true in the quantum mechanical analogy. [Pg.302]

Compared to the explicit Euler method (Eq. 15.9), note that the right-hand side is evaluated at the advanced time level tn+1- If f(t, ) is nonlinear then Eq. 15.22 must be solved iteratively to determine yn+. Despite this complication, the benefit of the implicit method lies in its excellent stability properties. The lower panel of Fig. 15.2 illustrates a graphical construction of the method. Note that the slope of the straight line between y +i and yn is tangent to the nearby solution at tn+, whereas in the explicit method (center panel) the slope is tangent to the nearby solution at t . [Pg.626]

The Levy construction [222] can be used to prove Hohenberg-Kohn theorems for the ground state of any such theory. It should be noted that any explicit model of the Hohenberg-Kohn functional F[p] implies a corresponding orbital functional theory. The relevant density function p(r) is that constructed from an OFT ground state. This has the orbital decomposition , as postulated by Kohn and Sham [205]. Unlike the density p,, for an exact A-electron wave function T, which cannot be determined for most systems of interest, the OFT ground-state density function is constructed from explicit solutions of the orbital Euler-Lagrange equations, and the theory is self-contained. [Pg.69]

This defines the fermion contribution to an isovector gauge current density. Although the Euler-Lagrange equation is gauge covariant by construction, this fermion gauge current is not invariant, because the matrix r does not commute with the 5(7(2) unitary transformation matrices. It will be shown below that the... [Pg.193]

Thus we see that the operator g is not strictly an angular momentum operator in the quantum mechanical sense, which is why we have assigned it a different symbol. More importantly for the present purposes, we cannot use the armoury of angular momentum theory and spherical tensor methods to construct representations of the molecular Hamiltonian. In addition, the rotational kinetic energy operator, equation (7.89), takes a more complicated form than it has for a nonlinear molecule where there are three Euler angles (rotational coordinates). [Pg.322]

To obtain the isomorphic Hamiltonian for a diatomic molecule, x is introduced as an independent variable and the coordinates of the particles which make up the molecule are measured in an axis system (x, y, z) whose orientation is described by the Euler angles (<-/>, 0, x) in the (X, Y, Z) axis system. We recall that we chose x to be zero in constructing the true Hamiltonian. The (x, y, z) axes are therefore obtained by rotation of the (x7, y, z ) axis system about the z (= z) axis through the angle x As a result, we have... [Pg.322]

The two Euler angles needed in order to construct a given rotation vector co, are computed using the following scheme ... [Pg.137]

Polyhedra related to the pentagonal dodecahedron and icosahedron In equation (1) for 3-connected polyhedra (p. 62) the coefficient of is zero, suggesting that polyhedra might be formed from simpler 3-connected polyhedra by adding any arbitrary number of 6-gon faces. Although such polyhedra would be consistent with equation (1) it does not follow that it is possible to construct them. The fact that a set of faces is consistent with one of the equations derived from Euler s relation does not necessarily mean that the corresponding convex polyhedron can be made. Three of the Archimedean solids are related in this way to three of the regular solids ... [Pg.65]

Johann Heinrich Lambert (1728-1777), mathematician, physicist and philosopher, was a tutor for the Earl P. v. Salis in Chur from 1748-1759, where he wrote his famous work on photometry [5.2]. In 1759 he became a member of the Bavarian Academy of Science and upon proposal by L. Euler became a member of the Berlin Academy of Science in 1765. Lambert wrote several philosophical works and dealt with subjects from all areas of physics and astronomy in his numerous publications. He presented the absolute zero point as a limit in the expansion of gases and constructed several air thermometers. In 1761 he proved that v and e are not rational numbers. His works on trigonometry were particularly important for the theory of map construction. [Pg.514]

It should be emphasized that the matrix representation becomes possible due to the Euler integration of the differential equations, yielding appropriate difference equations. Thus, flow systems incorporating heat and mass transfer processes as well as chennical reactions can easily be treated by Markov chains where the matrix P becomes "automatic" to construct, once gaining enough experience. In addition, flow systems are presented in unified description via state vector and a one-step transition probability matrix. [Pg.516]

The basic idea of the Runge-Kutta methods is illustrated through a simple second order method that consists of two steps. The integration method is constructed by making an explicit Euler-like trail step to the midpoint of the time interval, and then using the values of t and tp at the midpoint to make the real step across the whole time interval ... [Pg.1020]

Numerous predictor-corrector methods have been developed over the years. A simple second order predictor-corrector method can be constructed by first approximating the solution at the new time step using the first order explicit Euler method ... [Pg.1021]

In order to construct higher-order approximations one must use information at more points. The group of multistep methods, called the Adams methods, are derived by fitting a polynomial to the derivatives at a number of points in time. If a Lagrange polynomial is fit to /(t TO, V )i. .., f tn, explicit method of order m- -1. Methods of this tirpe are called Adams-Bashforth methods. It is noted that only the lower order methods are used for the purpose of solving partial differential equations. The first order method coincides with the explicit Euler method, the second order method is defined by ... [Pg.1021]

The convective terms were solved using a second order TVD scheme in space, and a first order explicit Euler scheme in time. The TVD scheme applied was constructed by combining the central difference scheme and the classical upwind scheme by adopting the smoothness monitor of van Leer [193] and the monotonic centered limiter [194]. The diffusive terms were discretized with a second order central difference scheme. The time-splitting scheme employed is of first order. [Pg.1070]


See other pages where Euler construction is mentioned: [Pg.223]    [Pg.224]    [Pg.224]    [Pg.223]    [Pg.224]    [Pg.224]    [Pg.669]    [Pg.19]    [Pg.2]    [Pg.240]    [Pg.273]    [Pg.2]    [Pg.379]    [Pg.285]    [Pg.135]    [Pg.70]    [Pg.75]    [Pg.19]    [Pg.322]    [Pg.180]    [Pg.491]    [Pg.67]    [Pg.4]    [Pg.366]    [Pg.1009]    [Pg.23]    [Pg.143]    [Pg.156]    [Pg.71]   
See also in sourсe #XX -- [ Pg.223 ]




SEARCH



Euler

© 2024 chempedia.info