Ethyl sebacate

Sebacoin has been prepared only by cyclization of methyl or ethyl sebacate with sodimn metal. ... 

Ethyl pentadecylate, 16, 37 Ethyl pentanehexacarboxylate, 10, 59 Ethyl phenylacetate, 16, 33 Ethyl -phenylacetoacetate, 18, 36 Ethyl -y-phenylbctyrate, 18, 25, 26 Ethyl phenylcyanopyruvate, 11, 40 Ethyl /J-phenylethyl ketone, 16, 49 Ethyl phenylmalonate, 16, 33 18, 84 Ethyl phenyloxaloacetate, 16, 33 Ethyl phthalimidomalonate, 14, 58 Ethyl pjmelate, 11, 42 17, 91 Ethyl propanetetracarboxylate, 10, 58 Ethyl propionate, 17, 34 Ethyl tso-propylmalonate, 11, 20, 21 Ethyl salicylate, 10, 51 11, 43 Ethyl sebacate, 14, 20 Ethyl sodium phthalimidomalonate, 14, 58... 

Ethyl 10-undecenoate ozonide was autoxidized at 95% in the absence of a catalyst. Diethyl sebacate, methyl ethyl sebacate, and dimethyl sebacate were detected after diazomethane treatment. When the ozonide was oxidized in acetone over platinum black and similarly treated with diazomethane, dimethyl sebacate could not be detected. 

To 86 5 g. (o 38 mole) of ethyl hydrogen sebacate (Org. Syn. 19, 45) is added slowly and with cooling 125-130 cc. of approximately 3 N potassium hydroxide. The solution is then diluted to approximately 250 cc., yielding a 1.5IV solution of potassium ethyl sebacate. 

The solution of potassium ethyl sebacate (Note 1) is poured into a 500-cc. tall type beaker provided with a cooling coil (Note 2), a thermometer, a stirrer, a platinum sheet anode 45-55 sq. cm. in area (Note 3), and two platinum wire cathodes (Note 4). To the solution 10 g. of monoethyl sebacate (Note 5) is added. 

Diethyl 1,16-hexadecanedicarboxylate has been prepared by the electrolysis of potassium ethyl sebacate.1... 

SYNS DIETHYLDECANEDIOATE DIETHYI l.lO-DECANEDIOATE ETHYL SEBACATE FEMANo. 2376 SEBACIC ACID, DIETHYL ESTER... 

It was also shown in the enantioselective synthesis of the macrolide patulolide that the anion of methyl p-tolyl sulfoxide was more reactive towards the imidazolide, prepared from the hemi ethyl sebacate, than the ester group (eq 7). 

Ethyl ester, Cl4HM04, ethyl sebacate, dr ethyl sebaeate. Colorless to yellowish fluid, dj° 0,965. bp about 307 with some decompn. rtjf 1.4369. Sol in about 700 parts cold, 50 parts boiling water misc with ale, ether and othet organic solvents. LDW orally in rats 14,470 mg/kg, P. M. Jenner et al. Food Cosmet. Toxicol. 2, 327 (1964). 

Berlin AR, Miller F (1976) Allergic contact dermatitis from ethyl sebacate in haloprogin cream. Arch Dermatol 112 1563-1564... 

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