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Ethanethiol iron complex

SC2H6, Ethanethiol, iron complexes, 21 39-46 SC2H8, Dimethyl sulfide, niobium complex, 21 16... [Pg.215]

The methods described here are based on the thermal stability of such clusters under CO pressure.4 In the case of Co2Fe(CO)9S, the complex itself is stable under hydroformylation conditions (130-180 °C, 50-150 bar CO and H2) and is formed under such conditions from almost every sulfur-containing substance, iron, cobalt, and carbon monoxide.1 Ethanethiol is used in the procedure as the sulfur source because of its reactivity. The dihydride cluster Fe3H2(CO)9S is not directly accessible by this method because it is a thermally much less stable species but the anion Fe3H(CO)9S" can be prepared in this way and its acidification yields the desired complex. [Pg.244]

See other pages where Ethanethiol iron complex is mentioned: [Pg.294]    [Pg.215]    [Pg.254]    [Pg.276]    [Pg.254]    [Pg.276]    [Pg.2113]    [Pg.5031]    [Pg.397]    [Pg.273]    [Pg.294]    [Pg.476]    [Pg.245]    [Pg.254]    [Pg.271]    [Pg.2112]    [Pg.5030]    [Pg.254]    [Pg.271]   
See also in sourсe #XX -- [ Pg.21 , Pg.39 ]

See also in sourсe #XX -- [ Pg.21 , Pg.39 ]



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