Ethane, rhodium complexes asymmetric hydrogenation

Ethane, (K)-l-cyclohexyl-L2-bis(diphenylphosphino)-rhodium complexes asymmetric hydrogenation, 6,253 Ethane, tetracyano-metal complexes, 2,263 Ethane, tetrakis(aminomethyl)-metal complexes, 2, 56 Ethane, tris[l, 1, l-(trisaminomethyl)]-complexes structure, 1,26... 

There are only two controlled kinetic studies of asymmetric hydrogenation, one of which was carried out using neutral diop complexes before the significance of ionization in polar solvents was fully appreciated, and, hence, the pathway studied is not necessarily the most efficient one. In the second, Halpern and Chan demonstrate that the kinetic form of the hydrogenation of methyl z-a-acetamidocinnamate catalyzed by the 1,2- /5(diphenylphosphino)-ethane rhodium cation in methanol is ... 

Gridnev, I. D. Higashi, N. Asakura, K. Imamoto, T. Mechanism of asymmetric hydrogenation catalyzed by a rhodium complex of (S, S)-bis(f-butylmethylphosphino)ethane. Dihydride mechanism of asymmetric hydrogenation. J. Am. Chem. Soc. 2000,122, 7183-7194. 

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