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Epoxide cyclization domino reaction

The question of oxidative cyclization versus a polyepoxide cascade in the biosynthesis of polyether natural products has been reviewed <1995AGE298>. Enzymatic domino reactions involving epoxide intermediates have been reviewed <2001CSR332>. The DNA-damaging activity of epoxides and other oxidized species has been examined using chemical models <1995ACR289>. [Pg.215]

Treatment of homo-allylic alcohols with catalytic MTO and hydrogen peroxide results in epoxidation followed by hydroxyl lactonization to yield substituted tetrahydrofurans in high yield (eq 14). Alcohols, acids and esters all undergo such domino epoxidation/cyclization reactions. ... [Pg.417]

Scheme 1.38. Domino epoxide-opening/rearrangemenl/cyclization reaction towards the total synthesis of (+)-stachyflin (1-152). Scheme 1.38. Domino epoxide-opening/rearrangemenl/cyclization reaction towards the total synthesis of (+)-stachyflin (1-152).
See other pages where Epoxide cyclization domino reaction is mentioned: [Pg.306]    [Pg.16]    [Pg.187]    [Pg.529]    [Pg.171]    [Pg.16]    [Pg.187]    [Pg.368]    [Pg.1350]    [Pg.1111]    [Pg.913]    [Pg.21]    [Pg.168]    [Pg.296]    [Pg.397]    [Pg.113]    [Pg.609]   
See also in sourсe #XX -- [ Pg.33 ]

See also in sourсe #XX -- [ Pg.33 ]



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Cyclization epoxide

Cyclization reactions

Cyclizations domino

Domino cyclization

Domino reactions

Domino reactions cyclizations

Epoxide reaction

Epoxides reactions

Reactions epoxidation

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