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Enzyme-triggered assembly

Enzyme-Triggered Self-Assembly Under Thermodynamic Control. 136... [Pg.128]

Fig. 4 Free energy diagram for the two possible situations in enzyme-triggered formation of supramolecular assembly. Left. The enzyme-catalysed reaction and self-assembly process are both favoured independently and therefore uncoupled. Right. Enzyme-triggered self-assembly under thermodynamic control formation of the building blocks is thermodynamically unfavoured in isolation and occurs in reversible fashion when coupled to a sufficiently stable self-assembled structure formation... Fig. 4 Free energy diagram for the two possible situations in enzyme-triggered formation of supramolecular assembly. Left. The enzyme-catalysed reaction and self-assembly process are both favoured independently and therefore uncoupled. Right. Enzyme-triggered self-assembly under thermodynamic control formation of the building blocks is thermodynamically unfavoured in isolation and occurs in reversible fashion when coupled to a sufficiently stable self-assembled structure formation...
Toledano S, Williams RJ, Jayawarna V, Ulijn RV (2006) Enzyme-triggered self-assembly of peptide hydrogels via reversed hydrolysis. J Am Chem Soc 128 1070-1071... [Pg.141]

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See also in sourсe #XX -- [ Pg.134 ]



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