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Endothermic process Describes processes

A heat flow calorimeter and the drop calorimetric method were used by Connor, Skinner, and Virmani to investigate the thermal decomposition of Cr(CO)6 at 514 K (the calibration was made with iodine as described above) [164], The only peak observed corresponded to an endothermic process ... [Pg.144]

Reaction 2.10 describes the loss of a radical, whereas reaction 2.11 corresponds to the loss of a molecule, thereby conserving the radical cation property of the molecular ion in the fragment ion. Bond breaking is a endothermal process and thus the potential energy of the fragment ion is usually located at a higher energy level (Fig. 2.4). [Pg.23]

Hydrate dissociation is of key importance in gas production from natural hydrate reservoirs and in pipeline plug remediation. Hydrate dissociation is an endothermic process in which heat must be supplied externally to break the hydrogen bonds between water molecules and the van der Waals interaction forces between the guest and water molecules of the hydrate lattice to decompose the hydrate to water and gas (e.g., the methane hydrate heat of dissociation is 500 J/gm-water). The different methods that can be used to dissociate a hydrate plug (in the pipeline) or hydrate core (in oceanic or permafrost deposits) are depressurization, thermal stimulation, thermodynamic inhibitor injection, or a combination of these methods. Thermal stimulation and depressurization have been well quantified using laboratory measurements and state-of-the-art models. Chapter 7 describes the application of hydrate dissociation to gas evolution from a hydrate reservoir, while Chapter 8 describes the industrial application of hydrate dissociation. Therefore in this section, discussion is limited to a brief review of the conceptual picture, correlations, and laboratory-scale phenomena of hydrate dissociation. [Pg.176]

In summary, to use Le Chatelier s principle to describe the effect of a temperature change on a system at equilibrium, treat energy as a reactant (in an endothermic process) or as a product (in an exothermic process), and predict the direction of the shift as if an actual reactant or product is added or removed. Although Le Chatelier s principle cannot predict the size of the change in A, it can correctly predict the direction of the change. [Pg.215]

Figure 5 shows the thermally induced (10-60°C) changes in the CHj stretching frequency of intact human SC plotted as a function of hydration and reheating. Corresponding data for the extracted lipid samples are depicted in Fig. 6. For SC, the frequency increased with temperature and showed a small, but definite, inflection point between 35 and 45°C. Under dry conditions, the midpoint was estimated to be 45°C, decreasing to a constant value of 35°C as the hydration level was increased. This behavior closely mimicked the calorimetric results described, suggesting that the 35°C inflection observed by IR corresponded to the same endothermic process measured by DSC. However, no evidence of a thermal transition at 35°C was observed by IR in the... Figure 5 shows the thermally induced (10-60°C) changes in the CHj stretching frequency of intact human SC plotted as a function of hydration and reheating. Corresponding data for the extracted lipid samples are depicted in Fig. 6. For SC, the frequency increased with temperature and showed a small, but definite, inflection point between 35 and 45°C. Under dry conditions, the midpoint was estimated to be 45°C, decreasing to a constant value of 35°C as the hydration level was increased. This behavior closely mimicked the calorimetric results described, suggesting that the 35°C inflection observed by IR corresponded to the same endothermic process measured by DSC. However, no evidence of a thermal transition at 35°C was observed by IR in the...
Strongly exo- or endothermic processes are generally carried out in multitube configurations, to permit heat removal/supply via a fluid medium. Within the tubes heat must be transferred at right angles to the flow axis this transfer can be described by a radial heat transfer coefficient in the structure itself, and a wall heat transfer coefficient, The overall heat transfer coefficient Oiot is then given, where the radial temperature profile is parabolic (see [9]) ... [Pg.401]

Using Scientific Diagrams Complete the diagram below using the following phrases solution, separated solvent + solute, separated solvent + separated solute, solvent + solute. Is the process described exothermic or endothermic ... [Pg.486]

Endothermic Describes processes that absorb heat energy. [Pg.40]

The second endothermic process (region B) is observed at the temperature higher 230 °C and ends at 270 °C. And during this process crystalline structure breaks and polyester melts. This transition, as crystallization, is phase. High temperature of PETP melting is described by specific role of aromatic nucleus linked by p - para-position [245]. [Pg.133]

How does the entropy of the surroundings change during an exothermic reaction An endothermic reaction Other than the examples cited in text, describe a spontaneous endothermic process. [Pg.677]

The classical route to SiC, the so-called Acheson process, has recently been described thoroughly by Schwetz [169]. It is well known that high-purity quartz sand and petroleum coke are used to get silicon carbide corresponding to the summarizing equation for this strongly endothermic carbothermjd reduction process (ArH = 618.5 KJ moP ) ... [Pg.103]

Endothermic Term describing a process or reaction that absorbs heat. [Pg.1256]


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