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Emf, dependence on concentration

In the voltaic cells we have looked at thus far, the reactive species at the anode has been different from the reactive species at the cathode. Cell emf depends on concentration, however, so a voltaic cell can be constructed using the same species in both half-cells as long as the concentrations are different. A cell based solely on the emf generated because of a difference in a concentration is called a concentration cell. [Pg.852]




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