Emery

Aluminium is not found free but its compounds are so widespread that it is the most abundant metal in the earth s crust. Aluminosilicates such as clay, kaolin (or china clay), mica and feldspar are well known and widely distributed. The oxide. AI2O3. occurs (anhydrous) as corundum and emery, and (hydrated) as bauxite. Cryolite. Na,AlF. (sodium hexafluoroaluminate). is found extensively in Greenland. 

Aluminium oxide occurs naturally as emery (an impure form) and as corundum. Corundum is a crystalline form which may be coloured by traces of impurity, for example as ruby (red) and sapphire (blue). Small synthetic rubies and sapphires have been made by heating alumina with the colouring oxide in an oxy-hydrogen flame. 

The compounds of greatest importance are aluminum oxide, the sulfate, and the soluble sulfate with potassium (alum). The oxide, alumina, occurs naturally as ruby, sapphire, corundum, and emery, and is used in glassmaking and refractories. Synthetic ruby and sapphire are used in lasers for producing coherent light. 

Abrasives have evolved iato an essential component of modem iadustry. Sandstone, emery, and comndum were the abrasives of choice until the late 1800s when artificial materials were developed. Today synthetic abrasives offer such improved performance that the natural ones have been largely replaced except for jobs where cost is paramount. In 1987 U.S. statistics (4) showed natural abrasive production to be about 7 million while that of cmde manufactured abrasives was over 182 million. Total value of abrasives and abrasive products worldwide is estimated to be over 6 biUion dollars. 

A sintered friction material is composed of a metal matrix, generally mainly copper, to which a number of other metals such as tin, zinc, lead, and iron are added. Important constituents include graphite and friction-producing components such as siHca, emery, or asbestos. 

Particulate Matter Other Phan Systemic Poisons. SUica and asbestos dust produce fibrosis. SUicon carbide, carbon (other than exhaust emissions), and emery are iuert dusts. Many organic dusts, eg, poUen, wood, and resius, cause aUergic reactions. Acids, alkaUes, fluorides, and chromates are irritants. 

Emery Industries Th. Goldschmidt AG C. P. Hall Company Kluber Chemie KG... 

HNC Henkel/Emery Corp. WVA Westvaco Corp., Polychemicals Div. 

There are two commercial solvent crystaUi2ation processes. The Emersol Process, patented in 1942 by Emery Industries, uses methanol as solvent and the Armour-Texaco Process, patented in 1948, uses acetone as solvent. The fatty acids to be separated are dissolved in the solvent and cooled, usually in a double-pipe chiller. Internal scrapers rotating at low rpm remove the crystals from the chilled surface. The slurry is then separated by means of a rotary vacuum filter. The filter cake is sprayed with cold solvent to remove free Hquid acids, and the solvents are removed by flash evaporation and steam stripping and recovered for reuse (10). 

Rhodium catalyst is used to convert linear alpha-olefins to heptanoic and pelargonic acids (see Carboxylic acids, manufacture). These acids can also be made from the ozonolysis of oleic acid, as done by the Henkel Corp. Emery Group, or by steam cracking methyl ricinoleate, a by-product of the manufacture of nylon-11, an Atochem process in France (4). Neoacids are derived from isobutylene and nonene (4) (see Carboxylic acids, trialkylacetic acids). 

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