Elements radio

Debieme A (1900) Sur un nouvel element radio-actif I actinium. Comptes Rendus de Seances de I academie de Sciences 130 906-908... 

See K. Fajans, Radio Elements and Isotopes. Chemical Forces and Optical Properties of Substances, McGraw-Hill, New York, 1931. 

Cesium was first produced ia the metallic state by electrolysis of a molten mixture of cesium and barium cyanides (2). Subsequentiy the more common thermochemical—reduction techniques were developed (3,4). There were essentially no iadustrial uses for cesium until 1926, when it was used for a few years as a getter and as an effective agent ia reduciag the electron work function on coated tungsten filaments ia radio tubes. Development of photoelectric cells a few years later resulted ia a small but steady consumption of cesium and other appHcations for cesium ia photosensing elements followed. 

Nuclear-physical methods ai e the basic ones in controlling environmental pollution which results from nucleai -power complexes and power plants work. Oil and gas production leads to the extraction of radio nuclides of natural origin in considerable amounts, which later spread from oil-slimes and water wastes in the neighborhoods of oil and gas producing entei prises. Similaidy, toxic and radioactive elements can pollute environment in case of mineral deposits extraction. 

The reaction of trifluoromethyl radicals, generated in a radio-frequency discharge process, with elemental mercury f/7i], mercury halides [174], dime-thylmercuiy [24], or HgO [175] has been used for the preparation of CFjHgX and (CF3)2Hg. Direct fluorination of dimethylmercury with elemental fluorine gives (CF3)2Hg [176],... 

What I hope to have added to the discussion has been a philosophical reflection on the nature of the concept of element and in particular an emphasis on elements in the sense of basic substances rather than just simple substances. The view of elements as basic substances, is one with a long history. The term is due to Fritz Paneth, the prominent twentieth century radio-chemist. This sense of the term element refers to the underlying reality that supports element-hood or is prior to the more familiar sense of an element as a simple substance. Elements as basic substances are said to have no properties as such although they act as the bearers of properties. I suppose one can think of it as a substratum for the elements. Moreover, as Paneth and before him Mendeleev among others stressed, it is elements as basic substances rather than as simple substances that are summarized by the periodic table of the elements. This notion can easily be appreciated when it is realized that carbon, for example, occurs in three main allotropes of diamond, graphite and buckminsterfullenes. But the element carbon, which takes its place in the periodic system, is none of these three simple substances but the more abstract concept of carbon as a basic substance. 

Soddy, F. The Chemistry of the Radio-Elements, part 1 Longmans, Green Co. London, 1914. 

We have also included R.F. (radio-frequency) current as a heating element, although it is only a heating method when employed with a suitable succeptor. Finally, one other method is listed for the sake of completeness, that of the oxy-hydrogen flame. It generates combustion products (H2O) but the RF- method can be used in any atmosphere... 

Soddy F (1913a) The radio-elements and the periodic law. Chemical News 107 97-99 Soddy F (1913b) Radioactivity. In Annual Reports on the Progress of Chemistry. The Chemical Society, London, p 262-288... 

The need to understand the processes operating on Earth, coupled to recent analytical advances, have ensured that the U-series nuclides have seen widespread application since the last Ivanovich and Harmon book (1992). This volume does not set out to repeat material in that book, but is an attempt to bring together the advances in the subject over the last ten years, highlighting the excitement and rapid expansion of U-series research. The scope of the various chapters in this book is laid out at the end of this introduction. The remainder of this chapter introduces some of the basic concepts of U-series geochemistry, the chemical behavior of the elements involved, and the half-lives of the U- and Th-series nuclides. This chapter is not intended to be an exhaustive summary of the nuclear or radio-chemistry of the U-series nuclides and for additional information, the reader is referred to Ivanovich (1992). 

Boltwood BB (1907) Note on a new radio-active element. Amer J Sci 24 370-372... 

Moulin V, Ouzounian G (1992) Role of colloids and humic substances in the transport of radio-elements through the geosphere. Appl Geochem (Suppl. Issue 1 179-186 Murakami T, Ohnuki T, Isobe H, Sato T (1997) Mobility of uranium during weathering. Am Mineral 82 888-899... 

Loring published chemistry books—Studies in Valency (1913), Atomic Theory (1921), Definition of the Principle of Equivalence (1922), and The Chemical Elements (1923). During the brief existence of the Alchemical Society, he published twenty articles (eight of them lead articles) in Chemical News on such subjects as atomic weight, the radio-atoms, the evolution of chemical elements, and a five-part Introduction to the Theory of Relativity. He also published seven correspondences in the journal, and Chemical News reviewed his Studies in Valency positively. 

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