Element fractionation resulting from planetary differentiation

Element fractionation resulting from planetary differentiation 

Planetary differentiation is a fractionation event of the first order, and it involves both chemical fractionation and physical fractionation processes. Planetary crusts are enriched in elements that occur in silicate minerals that melt at relatively low temperatures. Recall from Chapter 4 that the high solar system abundances of magnesium, silicon, and iron mean that the silicate portions of planetesimals and planets will be dominated by olivine and pyroxenes. Partial melting of sources dominated by olivine and pyroxene ( ultramafic rocks ) produces basaltic liquids that ascend buoyantly and erupt on the surface. It is thus no surprise that most crusts are made of basalts. Remelting of basaltic crust produces magmas richer in silica, eventually resulting in granites, as on the Earth. 

The formation of the Moon s crust, composed primarily of feldspar (the rock is called anorthosite) illustrates how physical fractionation can occur during differentiation. Early in its history, a significant portion of the Moon was melted to form a magma ocean. The first minerals to crystallize, olivine and pyroxene, sank because of their high densities and formed an ultramafic mantle. Once feldspar began to crystallize, it floated and accumulated near the surface to produce the crust. 

The Earth s crust and, indeed, the crusts of all differentiated bodies, are enriched in incompatible elements relative to their mantles. This reflects the partial melting of mantle material and extraction and transport of the basaltic melt to the surface. On Earth, further partial melting of the basaltic crust in the presence of water produces magma compositions even richer in silica (andesite and granite), which form the bulk of the continental crust. Because other differentiated bodies are effectively dry, this second level of differentiation did not occur. 

In experimental studies, metal-sulfide liquids form rounded globules that will sink through a silicate matrix that is itself partly molten (e.g. Walker and Agee, 1988). The density difference is sufficient that segregation of a metallic core though a mush of liquid and crystals should be rapid. However, sinking of metallic liquid through a solid or mostly 

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Element fractionation resulting from planetary differentiation... 

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