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Electron transfer reactions intramolecular long-distance

J. R. Miller, L. T. Calcaterra, and G. L. Closs, Intramolecular long-distance electron transfer in radical ions. The effects of free energy and solvent on the reaction rates, J. Am. Chem. Soc. 106 3047-3049 (1984). [Pg.385]

Miller, J. R., Calcaterra, L. T., Closs, G. L., Intramolecular Long distance Electron Transfer in Radical Anions. The Effect of Free Energy and Solvent on the Reaction Rates, J. Am. Chem. Soc., 1984, 106, 3047 3049. [Pg.487]

Electron-Transfer Reactions. It is well known that thermal and photochemical electron-transfer reactions exhibit characteristic pressure dependences and associated volumes of activation (see Sections II, III, and VI). It is therefore realistic to expect that photoinduced thermal electron-transfer reactions will also exhibit a characteristic pressure dependence that should reveal mechanistic information on the nature of the reaction. Recent interest in the mechanistic understanding of long-distance electron-transfer reactions prompted an investigation of the effect of pressure on intramolecular electron transfer in ruthenium-modified cytochrome c [151] (a typical example of a closely related intermolecular electron-transfer reaction was... [Pg.137]

Another interesting topic concerning radiation-induced reactions in proteins in aqueous solution concerns intramolecular long-distance electron transfer in proteins [85,98,101]. Respective studies were performed using pulse radiolysis... [Pg.294]

This mechanism requires at least two rapid electron transfer steps and, consequently, Ragsdale and co-workers initially proposed fast intramolecular electron transfer between CODH and ACS [137]. However, this is not compatible with the long distance that separates the ACS A-cluster and the CODH redox centers [90,91]. Under in vivo conditions another redox partner could be involved. In this scheme, it is tacitly assumed that CO is required for the first one-electron reaction as no paramagnetic species is detected upon reductive activation of the enzyme in the absence of CO [138]. [Pg.76]


See other pages where Electron transfer reactions intramolecular long-distance is mentioned: [Pg.295]    [Pg.324]    [Pg.326]    [Pg.245]    [Pg.166]    [Pg.175]    [Pg.178]    [Pg.4]    [Pg.6]    [Pg.190]    [Pg.154]    [Pg.2599]    [Pg.569]    [Pg.154]    [Pg.230]    [Pg.190]    [Pg.193]    [Pg.12]   
See also in sourсe #XX -- [ Pg.713 ]

See also in sourсe #XX -- [ Pg.713 ]

See also in sourсe #XX -- [ Pg.6 , Pg.713 ]




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Electron distance

Electron transfer intramolecular

Electron transfer long distance

Electron-transfer distances

Intramolecular distances

Intramolecular electronics

Long distance

Reaction distance

Transfer distances

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