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Electron-lattice interactions, organic

Superconductivity was first discovered in mercury by H. Kamerlingh Onnes in 1911 (329) and eluded attempts at explanation until, in 1957, Bardeen, Cooper, and Schrieffer formulated the BCS theory (29) based on an electron-lattice-electron interaction. This theory and two others [by W. A. Little (268) and H. Frohlich (152)] are briefly described a full review is beyond the scope of this article. Interest in this area has been heightened by the report of superconducting fluctuations in the one-dimensional organic material, tetrathio-fulvalenium tetracyanoquinodimethanide, (TTF)(TCNQ) (97). [Pg.29]

OPTICAL STUDIES OF THE INTERPLAY BETWEEN ELECTRON- LATTICE AND ELECTRON-ELECTRON INTERACTIONS IN ORGANIC CONDUCTORS AND SUPERCONDUCTORS... [Pg.129]

The charge transport in organic crystals is conventionally described either as a coherent or an incoherent process with respect to the interaction strength of the charge carrier with lattice vibration. In the weak electron phonon interaction... [Pg.321]

A systematic analysis of the electrostatic interactions in the crystals of 40 rigid organic molecules was undertaken by Price and coworkers (D. S. Coombes et al. 1996). In this work, distributed (i.e., local) multipoles up to hexadecapoles, obtained from SCF calculations with 6-31G basis sets, scaled by a factor of 0.9 to allow for the omission of electron correlation, are used in the evaluation of the electrostatic interactions. The experimental lattice constants and structures are reproduced successfully, the former to within a few percent of the experimental... [Pg.209]


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Electron-lattice interactions

Electron-lattice interactions, organic materials

Electronic interactions

Lattice organization

Organ interactions

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