Electrochemistry organometallic

The present volume, the thirty-fourth in the series, surveys research on organic reaction mechanisms described in the literature dated December 1997 to November 1998. In order to limit the size of the volume, we must necessarily exclude or restrict overlap with other publications which review specialist areas (e.g. photochemical reactions, biosynthesis, electrochemistry, organometallic chemistry, surface chemistry and heterogeneous catalysis). In order to minimize duplication, while ensuring a comprehensive coverage, the Editors conduct a survey of all relevant literature and allocate publications to appropriate chapters. While a particular reference may be allocated to more than one chapter, we do assume that readers will be aware of the alternative chapters to which a borderline topic of interest may have been preferentially assigned. 

Moran, M. Pascual. M.C. Cuadrado, I. Losada. J. (Dimethylamino)dimethylsilyl-substituted dimeric and siloxanyl polymeric compounds containing [(ti -C5R4)-Fe(CO)(p-CO)]2 (R = H. Me) moieties. Synthesis, characterization, and electrochemistry. Organometallics 1993. 72 811-822. 

Part II Macromolecules Catalysis Colloid Science Electrochemistry Electron Spin Resonance Environmental Chemistry Genetal and Synthetic Methods Mass Spectrometry Nuclear Magnetic Reson n e Organometallic Chemistry Organophosphorus Chemistry Photochemistry... 

A review9 with more than 37 references includes an examination of symmetry groups and chirality conditions for C60 and C70 bonded to one or two metals in rf and/or rf fashion. Palladium and platinum rf complexes of C6o and C70 are described (novel synthesis, NMR spectra, electrochemistry) as well as first optically active organometallic fullerene derivatives. 

Works by Dessy and coworkers provide a comprehensive treatment of the electrochemistry of the metal-metal bonds in organometallic compounds. This includes the scission144 and formation145 of metal-metal bonds and also the reactivities and nucleophilicity of... 

Electrochemistry, organic, structure and mechanism in, 12, 1 Electrode processes, physical parameters for the control of, 10, 155 Electron donor-acceptor complexes, electron transfer in the thermal and photochemical activation of, in organic and organometallic reactions. 29, 185 Electron spin resonance, identification of organic free radicals, 1, 284 Electron spin resonance, studies of short-lived organic radicals, 5, 23 Electron storage and transfer in organic redox systems with multiple electrophores, 28, 1 Electron transfer, 35, 117... 

We now wish to illustrate the role of electrochemistry in various fields of inorganic chemistry ranging from organometallics to coordination chemistry, from material science to biomimetics. The present chapter is devoted to metallocenes. 

Head of the Department of Chemistry at the University of Siena since 1996, Professor Piero Zanello has more than 20years experience in electrochemistry of organometallic and coordination compounds. He has been part of numerous national and international research groups, and is a well-known lecturer and author of scientific papers. 

A. J. L. Pombeiro, J. McCleverty, (Eds.), Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds NATO AS I Series, Kluwer, Dordrecht, The Netherlands, 1993. 

In the mid-1960s, Dessy and coworkers [12, 13] provided an extensive survey of the anodic and cathodic reactions of transition metal organometallic species, including binary (homoleptic) carbonyls, and this provided a stimulus for many later detailed studies. Whereas the electrochemistry of heteroleptic transition metal carbonyls is covered elsewhere in this volume, that of the binary carbonyls, which is covered here, provides paradigms for the electrochemistry of their substituted counterparts. A key aspect is the generation of reactive 17-electron or 19-electron intermediates that can play key roles in the electrocatalytic processes and electron-transfer catalysis of CO substitution by other ligands. 

In the last 37 years a nnmber of chapters and reviews have been pnblished on electrochemistry of organoelemental and organometallic compounds discnssing electrode reactions of organomagnesinm componnds, in particnlar Grignard reagents, the most important ones... 

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