Electrochemistry of transition metal hexacyanoferrates

Electrochemistry of transition metal hexacyanoferrates Amperometric sensors for redox-inactive cations and electroactive componnds... 

Mechanisms of electrochemical reactions of different systems, including transition metal complexes, were examined with a special attention paid to double layer effects and problems of generation and decay of intermediates which arise in such reactions. Electrodes modified with thin films of transition metal hexacyanoferrates and conducting polymers were investigated, also solid state electrochemistry in the absence of external supporting electrolyte were developed. Charge propagation rate in such mixed-valent solid systems and their electrocatalytic properties were studied. 

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