Electrochemical determination of equilibrium constants

The Electrochemical Determination of Equilibrium Constants for Isotope-Exchange Reactions 

Department of Chemistry, University of California, Davis, Calif. 95616 I. Introduction 

The difference procedure outlined above is not useful, as suchjfor elements other than hydrogen, because the difference between the two values is then usually smaller than the sum of the absolute errors in the ° values for the two isotope cells. However, if we use electrochemical double cells without liquid 

ACS Symposium Series American Chemical Society Washington, DC, 1975. 

Pt)lDCl(D20) AgCl(s) Ag(s) AgCl(s)lHCl(Ha0) lfe(g,Pt) (k) the overall cell reaction for which is reaction (5) above. 

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