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Electric component , of electromagnetic

The fundamental equation (1) describes the change in dipole moment between the ground state and an excited state jte expressed as a power series of the electric field E which occurs upon interaction of such a field, as in the electric component of electromagnetic radiation, with a single molecule. The coefficient a is the familiar linear polarizability, ft and y are the quadratic and cubic hyperpolarizabilities, respectively. The coefficients for these hyperpolarizabilities are tensor quantities and therefore highly symmetry dependent odd order coefficients are nonvanishing for all molecules but even order coefficients such as J3 (responsible for SHG) are zero for centrosymmetric molecules. Equation (2) is identical with (1) except that it describes a macroscopic polarization, such as that arising from an array of molecules in a crystal (10). [Pg.59]

The interaction bet veen electromagnetic vaves and matter is quantified by the two complex physical quantities - the dielectric permittivity, s, and the magnetic susceptibility, fi. The electric components of electromagnetic waves can induce currents of free charges (electric conduction that can be of electronic or ionic origin). [Pg.9]


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