Eglington-Glaser reaction

EDA complex formation, phase transitions 339 edge dislocation, Volterra process 419 effusity, phase transitions 320 Eglington-Glaser reaction, synthesis 99 eigenwaves, SLM 764 Einstein diffusivity-viscosity law 585... 

Some of the most useful synthetic transformations of terminal alkynes involve intermolecular and intramolecular homo- and cross-coupling reactions between their. sp-carbon centers, leading to butadiyne or polyyne derivatives. The two most widely used and practical systems are (i) oxidative homocoupling reactions, i.e. Glaser and Eglington reactions and (ii) heterocoupling reactions, i.e. Chodkiewicz-Cadiot coupling of a terminal alkyne with a haloalkyne. 

Organic reactions in the solid state, e. g. Baeyer-Villiger, Reformatsky, Luche, Glaser, Eglington, Wittig, Brown. Michael, Robinson often more efficient than in solution. 

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