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E -isomer

Tine force field was then used to predict the results for fhe addition of the E and Z isomers c Ihe enol boronate of butanone (R = Me) to ethanol (R = Me). The relevant transitio. Iructures are shown in Figure 11.34. A Boltzmann distribution, calculated at the ten perature of the reaction (—78°C), predicted that the Z isomer would show almost complel syn selectivity syn anti = 99 1) and that the E isomer would be selective for the an product anti syn = 86 14). These results were in good agreement with the experunenti... [Pg.627]

The widespread use of cinnamic derivatives has led to the pursuit of reUable methods for thek dkect synthesis. Commercial processes have focused on condensation reactions between ben2aldehyde and a number of active methylene compounds for assembly of the requisite carbon skeleton. The presence of a disubstituted carbon—carbon double bond in the sidechain of these chemicals also gives rise to the existence of two distinct stereoisomers, the cis or (Z)- and trans or (E)- isomers ... [Pg.173]

Physical and Chemical Properties. Cinnamic acid is generally encountered as the thermodynamically favored (E)-isomer. (H)-Cinnamic acid [140-10-3] is an off-white soHd having the properties outlined in Table 1 (6,7). [Pg.173]

The behaviour of /S-oxovinylazides is quite similar to those above. The Z isomer (556), formed from the /S-halo carbonyl compound and sodium azide, is unstable losing N2 and forming the isoxazole (557) in an anchimerically assisted concerted reaction (75AG(E)775, 78H(9)1207). At moderate temperatures (50-80 °C) the E isomer formed acylazirines which at higher temperatures rearranged to oxazoles and isoxazoles. [Pg.163]

N,N-Dimethy1aniline from Nakarai Chemicals was dried over calcium hydride and freshly distilled. Three molar equivalents of N,N-dimethylaniline are used to achieve complete conversion of the n-butyllithium, because In the present particular case free n-butyllithium, if present, causes the isomerization of the (Z)-alkene to the (E)-isomer. [Pg.42]

Prolonged reaction time causes the isomerization of (Z)-e-[2-(N,N-dimethylam1no)phenyl]styrene to the (E)-isomer. [Pg.43]

Isomer distribution and purity were assessed by GC (see Note 5). The NMR spectra (in CCI4) for the pure isomers are as follows E-isomer S 5.71... [Pg.183]

The possible presence in the 4-chloro-4-hexenyl trifluoroacetate of small amounts of two cis-trans pairs of products of addition of trifluoroacetic to the triple bond without concomitant halogen shift remains speculative. In any event these compounds would be removed as ketones upon hydrolysis of the trifluoroacetate. Both the 4-chloro-4-hexenyl trifluoroacetate and the alcohol resulting from its hydrolysis have been shown to contain 9% of the (E) isomer. In the present study the hydrogen decoupled magnetic resonance spectra of the ester and alcohol were shown to contain peaks attributable to approximately 9% of E) isomer. [Pg.29]

E-Cyclooctene is also significantly straine4 but less so than -cycloheptene. As the ring size is increased, the amount of strain decreases. The. E-isomers of both cyclononene and cyclodecene are less stable than the corresponding Z-isomers, but for cycloundecene and cyclododecene, the E-isomers are the more stable. Table 3.10 gives data concerning the relative stability of the C7 through C12 cycloalkenes. [Pg.165]

As shown in Fig. 13.10, the absorption spectra of Z- and -stilbene differ substantially, with the E isomer absorbing more strongly at A > 280 nm. Thus, the composition of the photostationaiy state can be controlled by altering the wavelength of the irradiation, as indicated by the equation on p. 766. ... [Pg.767]

Aromatic compounds such as toluene, xylene, and phenol can photosensitize cis-trans interconversion of simple alkenes. This is a case in which the sensitization process must be somewhat endothermic because of the energy relationships between the excited states of the alkene and the sensitizers. The photostationary state obtained under these conditions favors the less strained of the alkene isomers. The explanation for this effect can be summarized with reference to Fig. 13.12. Isomerization takes place through a twisted triplet state. This state is achieved by a combination of energy transfer Irom the sensitizer and thermal activation. Because the Z isomer is somewhat higher in energy, its requirement for activation to the excited state is somewhat less than for the E isomer. If it is also assumed that the excited state forms the Z- and -isomers with equal ease, the rate of... [Pg.769]

The 5-(E)-isomer of PGI2 was also unambiguously synthesized in two different approaches (Ref. 2, 3). [Pg.282]

At room temperature, base-catalyzed addition of thiophenol to phenyl trifluo-romethyl acetylene gives exclusively (Z)-3-phenyl-3-phenylthio-l,1,1-tnfluoro-propene. At 150 °C, the predominant isomer is the E isomer (64%), with 23% of the Z isomer and 13% of the other two regioisomers [4] (equation 5). [Pg.758]

Examples of perfluoroalkyl iodide addition to the triple bond include free radical addition of perfluoropropyl iodide to 1 -heptyne [28] (equation 21), thermal and free radical-initiated addition of lodoperfluoroalkanesulfonyl fluorides to acetylene [29] (equation 22), thermal addition of perfluoropropyl iodide to hexa-fluoro 2 butyne [30] (equation 23), and palladium-catalyzed addition of per-fluorobutyl iodide to phenylacetylene [31] (equation 24) The E isomers predominate in these reactions Photochemical addition of tnfluoromethyl iodide to vinylacetylene gives predominantly the 1 4 adduct by addition to the double bond [32] Platinum catalyzed addition of perfluorooctyl iodide to l-hexyne in the presence of potassium carbonate, carbon monoxide, and ethanol gives ethyl () per fluorooctyl-a-butylpropenoate [JJ] (equation 25)... [Pg.763]

Figure 24.9 Cluster carbonyls of rhenium containing an encapsulated carbon atom, (a) Octahedral [HjReeC-(C0)i8] . (b) Monocapped octahedral [Re7C(CO)2i] . (c) tran -bicapped octahedral [RegC-(CO)24] . (d) and (e) isomers of [Re7HC(CO)2i] differing in the position of their /r-H atom. Figure 24.9 Cluster carbonyls of rhenium containing an encapsulated carbon atom, (a) Octahedral [HjReeC-(C0)i8] . (b) Monocapped octahedral [Re7C(CO)2i] . (c) tran -bicapped octahedral [RegC-(CO)24] . (d) and (e) isomers of [Re7HC(CO)2i] differing in the position of their /r-H atom.
Hydrazones of 3-hydroxy-2-acetylbenzo[fe]furan are reported to exist as aminovinylketones 33 and 34 (90ZOR1540). The ratio of (Z, E) isomers depends upon and R. ... [Pg.100]

Reaction of nitro-2f/-chromene derivatives 134 with 135 in methanol at room temperature afforded a mixture of the Z-isomer 136 and tricyclic compound 137, which could be formed by denitrocyclization reaction of the corresponding primarily formed E-isomer and the following dehydrogenation (Eq. 15). The structural identification was based on the MS and H-NMR, however, it is not sufficiently documented and similar examples are not known (91IJC(B)297). [Pg.204]


See other pages where E -isomer is mentioned: [Pg.226]    [Pg.628]    [Pg.628]    [Pg.224]    [Pg.881]    [Pg.430]    [Pg.323]    [Pg.325]    [Pg.14]    [Pg.48]    [Pg.51]    [Pg.51]    [Pg.54]    [Pg.173]    [Pg.163]    [Pg.182]    [Pg.767]    [Pg.768]    [Pg.322]    [Pg.300]    [Pg.306]    [Pg.596]    [Pg.224]    [Pg.881]    [Pg.55]    [Pg.301]    [Pg.1015]    [Pg.126]    [Pg.147]    [Pg.149]    [Pg.259]    [Pg.12]    [Pg.126]   
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See also in sourсe #XX -- [ Pg.39 , Pg.87 ]

See also in sourсe #XX -- [ Pg.42 , Pg.43 ]

See also in sourсe #XX -- [ Pg.338 ]

See also in sourсe #XX -- [ Pg.75 ]




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E- and Z-isomers

E/Z isomers

Separation of Z and E Isomers

Sequence rules E,Z alkene isomers and

The E-Z Convention for Cis- Trans Isomers

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