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Dynamic kinetic resolution carbanion

Scheme5.73. Dynamic kinetic resolution via configurationally labile carbanions [283, 538, 539],... Scheme5.73. Dynamic kinetic resolution via configurationally labile carbanions [283, 538, 539],...
For configurationally unstable carbanions , a (thermodynamically driven) equiUbration between diastereomeric isomers is the method of choice, if the difference in free energy is large enough (>2 kcabmol ). In rare cases, a dynamic kinetic resolution is possible by preferential crystallization of one diastereomer. [Pg.64]

See other pages where Dynamic kinetic resolution carbanion is mentioned: [Pg.1097]    [Pg.198]    [Pg.1031]    [Pg.163]    [Pg.9]    [Pg.141]    [Pg.142]    [Pg.180]    [Pg.180]    [Pg.208]    [Pg.210]    [Pg.324]   
See also in sourсe #XX -- [ Pg.200 , Pg.201 ]



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