Dynamic Combinatorial Chemistry for Catalytic Applications

Dynamic Combinatorial Chemistry. Edited by Joost N. H. Reek and Sijbren Otto 2010 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim ISBN 978-3-527-32122-3 

Marcus theory describes the reaction pathway as the result of two intersecting parabola [4], the transition state being on the intersection of these. If the reaction 

A selechon procedure based on the reachon intermediate (or an analog) is based on the destabilization of the intermediate with respect to the transihon state. In an early hansihon state reachon path, the destabUizahon of the transihon state wih be close to that of the intermediate and is therefore less effechve as the 

Libraries of Cage Molecules and Dynamic Selection of Hosts/Cuests 

This type of binding event could be relevant for the stabilization of transition states, and analogs thereof, for coupHng reactions. 

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