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Dithiooxamides primary amines

Heating of dithiooxamide (26) with primary amines yields the corresponding iV-alkyl derivatives (27) the reaction is catalyzed by acid with even CO2 being effective (equation 15). ... [Pg.425]

In a process reminiscent of isonitrile hydrolysis, dichlorocarbene as generated from CHCI3 reacts with HaS in the presence of primary or secondary amines to yield thioformamides (79 equation 37). If pressure is employed, CCI4 or CI3CCCI3 can also be used with the latter giving dithiooxamides (27), e.g. with BuNHa, 65% of BuNHCSCSNHBu. 24... [Pg.432]

See other pages where Dithiooxamides primary amines is mentioned: [Pg.915]   
See also in sourсe #XX -- [ Pg.6 , Pg.425 ]

See also in sourсe #XX -- [ Pg.425 ]

See also in sourсe #XX -- [ Pg.6 , Pg.425 ]

See also in sourсe #XX -- [ Pg.425 ]



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Amination primary

Amines primary

Dithiooxamid

Dithiooxamide

Dithiooxamides

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