Dithiocarbonates, aminolysis

Aminolysis of phenyl dithioacetates, pyridinolysis of ( -ethyl dithiocarbonates, reaction of pyrrohdine with O-ethyl 5-aryl dithiocarbonates, aminolysis of chlorothionformates," pyridinolysis of alkyl aryl thioncarbonates, reaction of anionic nucleophiles with nitrophenyl benzoate and its sullur analogues, hydrolysis of methyl benzoate and phenyl acetate containing SMe, SOMe and SOaMe substituents, solvolysis of phenyl chlorothioformate, synthesis of new thiadiazoles, examination of a neighboming sulfonium group in ester hydrolysis,hydrolysis of V-type nerve agents, and the reactions of peroxymonosulfate ion with phosphorus(V) esters have all been looked at previously in this review. 

Carbamates by Aminolysis of Carbonate or Dithiocarbonate Esters Diethyl carbonate has been employed for the cydocarbamation of various amino alcohols. The reaction is catalyzed by basic substances, such as sodium methoxide, magnesium methoxide, potassium hydroxide, or sodium or potassium carbonates. Sodium methoxide in xylene [485-487], or potassium or sodium carbonate under reflux [488-493] are the preferred reaction conditions. The reaction has wide scope and synthetic utility. 

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