Distillation velocity

In molecular distillation, the permanent gas pressure is so low (less than 0 001 mm. of mercury) that it has very little influence upon the speed of the distillation. The distillation velocity at such low pressures is determined by the speed at which the vapour from the liquid being distilled can flow through the enclosed space connecting the still and condenser under the driving force of its own saturation pressure. If the distance from the surface of the evaporating liquid to the condenser is less than (or of the order of) the mean free path of a molecule of distillate vapour in the residual gas at the same density and pressure, most of the molecules which leave the surface will not return. The mean free path of air at various pressures is as follows —... 

Different operating parameters were varied, such as the feed and the distillate inlet temperatures, the feed and the distillate velocities, the feed concentration. Table 13.10 shows the ranges investigated. 

The highest value of the distillate flux was around 50 kg wr h at a feed temperature of 60°C and at a feed velocity of 0.062 m s . The increase of flux observed at higher distillate velocities was lower than that obtained when operating at higher feed velocities. 

Many experimental studies of entrainment have been made, but few of them have been made under actual distillation conditions. The studies are often questionable because they are hmited to the air-water system, and they do not use a realistic method for collecting and measuring the amount of entrainment. It is clear that the dominant variable affecting entrainment is gas velocity through the two-phase zone on the plate. Mechanisms of entrainment generation are discussed in the subsection Liquid-in-Gas Dispersions. ... 

Bakowsld [B/ Chem. Eng., 8, 384, 472 (1963) 14, 945 (1969)]. It is based on tbe assumption that tbe mass-transfer rate for a component moving to tbe vapor phase is proportional to tbe concentration of tbe component in tbe liquid and to its vapor pressure. Also, tbe interfacial area is assumed proportional to liquid depth, and surface renewal rate is assumed proportional to gas velocity. The resulting general equation for binaiy distillation is... 

Breakup in a highly turbulent field (L/velocity) ". This appears to be the dominant breakup process in distillation trays in the spray regime, pneumatic atomizers, and high-velocity pipehne contactors. 

TABLE 14-13 Dependency of Distillation Flood Velocity on Physical Properties and Tray Open Area... 

Figure 11.10 Effect of pH of distilled water on erosion-corrosion of carbon steel at 122°F (50°C) (velocity, 39 ft/s, 12 m/s). (SOURCE M. G. Fontana and N. D. Greene, Corrosion Engineering, 2d ed., 1978, p. 75. Reprinted with permission from McGraw-Hill, Inc.)...

Brenn-fieck, m. focus burned spot, -gas, n. combustible gas, fuel gas. -gerste, /. distilling barley, -geschwindigkeit, /. velocity of combustion or of burning or of distillation. 

Fig. 8.12 Effect of applied stress intensity upon crack velocity for high-strength (180 GN/m UTS) quenched and tempered steel (AFC 77) in distilled water (after Spicdel )...

No mechanism for cracking in N2O4 has been established . In organic media crack velocities are similar to those obtained in distilled water. Lowering the water content results in lower velocities. Not all authors attribute failures in organic liquids to the residual moisture . Furthermore, part of the fracture may be transgranular . Water additions to methanol increase crack velocities as do halide additions. In oils velocities are similar to those in organic liquids and distilled water. 

A vapor phase process for deparaffmization of light gas oils performed by the BP works in this way The gas oil, boiling range 230-320°C, is passed over a 5-A molecular sieve at 320°C and a pressure of 3.6 bar. The space velocity is 0.63 vol liquid gas oil per vol molecular sieve and per hour, [liquid hourly space velocity (lhsv) = 0.63] the adsorption period takes 6 min. Together with the gas oil vapor 120 vol N2 per vol liquid gas oil is led over the sieve as carrier and purge gas. After the adsorption period the loaded molecular sieve is purged at the same temperature with pure N2 for 6 min. Subsequently, the adsorbed /z-alkanes are desorbed by 1 vol liquid /z-pentane per vol molecular sieve and per hour. The /z-pentane is recovered from the /z-alkane//z-pentane mixture by simple distillation [15]. The IsoSiv process of the Union Carbide Corporation works in a similar way [16]. The purity of the isolated /z-alkanes is >98%. 

As a result of the diffusional process, there is no net overall molecular flux arising from diffusion in a binary mixture, the two components being transferred at equal and opposite rates. In the process of equimolecular counterdiffusion which occurs, for example, in a distillation column when the two components have equal molar latent heats, the diffusional velocities are the same as the velocities of the molecular species relative to the walls of the equipment or the phase boundary. 

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