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Dissociation energies of molecules

These so-called Birge-Sponer plots can also be used to determine dissociation energies of molecules. By linearly extrapolating the plot of experimental AEVj values to... [Pg.265]

The equations used in our study of the thermodynamics and kinetics of thermal electron reactions using the ECD and NIMS are presented. The ECD and NIMS methods were developed in our laboratories. These are used to determine the rate constants, electron affinities, partition function ratios, and bond dissociation energies of molecules and energies for the formation of complexes of anions. The general kinetic model for the ECD and negative-ion mass spectrometry is presented. Molecules will be classified using example data. [Pg.47]

Q/ is the bond strength between a metal atom and Aj the dissociation energy of molecule AB and Dmm the bond strength between two metal atoms. [Pg.206]

Comparison with qs.(3.28) shows that Bq.(3.34) equals the dissociation energy of molecule ABx... [Pg.208]

Dc is the dissociation energy of molecule c, Dc + Dd Dc — Dd> is heat effect of an exchange reaction. Formulas (36), (37) express the chemical-equilihrium constants weU known from thermodynamics and hold only for Maxwell-Boltzmarm distributions over velocity and internal energy. [Pg.121]


See other pages where Dissociation energies of molecules is mentioned: [Pg.200]    [Pg.506]    [Pg.222]    [Pg.506]    [Pg.145]    [Pg.2089]    [Pg.495]    [Pg.412]    [Pg.299]    [Pg.145]    [Pg.66]    [Pg.988]    [Pg.316]    [Pg.451]    [Pg.40]    [Pg.72]    [Pg.401]    [Pg.81]    [Pg.12]    [Pg.988]    [Pg.119]    [Pg.252]    [Pg.400]    [Pg.393]    [Pg.167]    [Pg.388]   


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