Displaced number states , quantum optics

This work is intended as an attempt to present two essentially different constructions of harmonic oscillator states in a FD Hilbert space. We propose some new definitions of the states and find their explicit forms in the Fock representation. For the convenience of the reader, we also bring together several known FD quantum-optical states, thus making our exposition more self-contained. We shall discuss FD coherent states, FD phase coherent states, FD displaced number states, FD Schrodinger cats, and FD squeezed vacuum. We shall show some intriguing properties of the states with the help of the discrete Wigner function. 

The necessary derivations with respect to the small displacements can be performed either numerically, or, more recently, also analytically. These analytical methods have developed very rapidly in the past few years, allowing complete ab initio calculation of the spectra (frequencies and intensities) of medium sized molecules, such as furan, pyrrole, and thiophene (Simandiras et al., 1988) however, with this approach the method has reached its present limit. Similar calculations are obviously possible at the semi-empirical level and can be applied to larger systems. Different comparative studies have shown that the precise calculation of infrared and Raman intensities makes it necessary to consider a large number of excited states (Voisin et al., 1992). The complete quantum chemical calculation of a spectrum will therefore remain an exercise which can only be perfomied for relatively small molecule. For larger systems, the classical electro-optical parameters or polar tensors which are calibrated by quantum chemical methods applied to small molecules, will remain an attractive alternative. For intensity calculations the local density method is also increasing their capabilities and yield accurate results with comparatively reduced computer performance (Dobbs and Dixon, 1994). 

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